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Southern Ocean Sea Ice Microplastic Analysis - PanAntarctic study 2004-2022
The purpose of this study was to quantify microplastic pollution in the Southern Ocean through the analysis of sea-ice cores from several distinct regions around the Antarctic continent. We analysed 19 sea-ice cores from 10 individual research expeditions across distinct Southern Ocean regions: The Antarctic Peninsula, the Bellinghausen Sea, the Weddell Sea, Queen Maud Land, Prydz Bay, Wilkes Land, Mawson Sea, the Ross Sea, and McMurdo Sound, and sampled between austral summers 2004-2022. The campaigns and drill dates are as follows: ISPOL (Dec 2004), SIMBA (Oct 2007), YROSIAE (Dec 2011 and Nov 2012), SIPEX II (Oct 2012), DAVIS (Nov 2015), AAV2 (Dec 2016), PIPERS (May 2017), AWECS (June 2017), REKT (Jan 2021), and DML (Jan 2022). Abundance, chemical composition and size data for microplastics was obtained from these ice-core samples by means of Fourier-transform Infrared Spectroscopy (FTIR). Sample analysis was conducted with OPUS 8.7 software (Bruker), and the collated OPUS data was exported as an ENVI file and particle analysis was conducted with Purency Microplastic Finder (PMF) an automated analysis software for μFTIR imaging. In the provided excel data set, the sheet labelled “total polymer counts” provides data directly from Purency Microplastic Finder software, including polymer type, pixel size, area, length and width and denoted individually for each ice-core drill site. The sheet labelled “MP concentrations” denotes the abundance of microplastic particles per core, the quantity of sea-ice meltwater filtered, and the integrated abundances of microplastics across drill seasons, sites, and ice textures. The R data tab in data collated from the previous sheets to perform statistical analyses in R to determine if there were significant differences in medians across ice types, pan-Antarctic regions, and seasons. See the downloadable dataset for more information.
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Microplastics in sea ice methodology cores
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Five subsections of Antarctic ice cores were used to create a new methodology for analyzing microplastics in sea ice.
Mechanical and microstructural data from ice deformation experiments with a change in temperature partway
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This dataset contains data collected during and after a series of ice deformation experiments. Seven of the experiments are controls, run at a constant temperature of either -2, -7 or -10 degrees celsius, and four involve a change in temperature partway through the experiment. Vertical displacement and temperature data were collected during the experiments, and microstructural data (fabric analyser thin sections) were collected at the conclusion of each experiment. The experimental methods and our interpretations are described thoroughly in Craw, et al. (in prep). In folder mechanical_data: - One .csv file for each experiment containing a header with information on experimental conditions, and columns of data corresponding to time (hours), vertical displacement (mm), and temperature (degrees celsius) throughout the experiment. This is raw data, there will be points recorded from before weights were added at the beginning of the experiment, and after the temperature was lowered at the end. in folder microstructural_data: - One .mat file for each experiment, containing microstructural data (spatially indexed Euler orientations) formatted to be read by the MTEX toolbox (https://mtex-toolbox.github.io/). There is also a file for an example of the starting material, "standard" laboratory ice. These data are converted from the .cis files which are generated by the G50 fabric analyser. - One .m script (plot_microstructural_data.m) containing commands for plotting spatial maps, histograms of grain size distribution and pole figures of c-axis orientation from the .mat files in this directory.
Circum-Antarctic landfast sea ice extent, 2000-2018
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This dataset (provided as a series of CF-compatible netcdf file) consists of 432 consecutive maps of Antarctic landfast sea ice, derived from NASA MODIS imagery. There are 24 maps per year, spanning the 18 year period from March 2000 to Feb 2018. The data are provided in a polar stereographic projection with a latitude of true scale at 70 S (i.e., to maintain compatibility with the NSIDC polar stereographic projection).
Sea ice data - Bio-optics and physics measurements from Scott Base and McMurdo Sound 2014
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As part of Australian Antarctic Science project # 4298 and Antarctica New Zealand project K131A, a total number of 24 sea ice sites were sampled for bio-optical measurements along 2 transects on land-fast sea ice in McMurdo Sound (Antarctica) during November 2014. Measurements included hyperspectral surface irradiance measurements (TriOS ASS) as well as under-ice radiance measurements using a TriOS ARC (350 – 900 nm, 3.3 nm resolution) radiometer mounted to an L-arm. After completion of radiometric measurements, snow thickness was measured with a ruler and an ice core was collected directly above the radiometer location. Sea-ice freeboard (tape measure) and ice thickness (ice core length) were recorded. Ice core (9 cm internal diameter) bottom sections (lowermost 0.1 m of ice cores) were collected and were used for determination of algal pigment content (using HPLC) and spectral ice algal absorption coefficients (ap, ad, aph). Sea ice physical properties including vertical profiles of ice temperature and salinity profiles were collected at some specific locations along the transects, which were sampled near Little Razorback Island and near Cape Evans, McMurdo Sound.
Amery Ice Shelf - hot water drill borehole, AM05 Seabird MicroCAT CTD moorings at three depths in ocean cavity beneath the shelf - 2011-2013 data
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AM05 borehole drilled December 2009. Data being collected at annual re-visits to site. Consult Readme file for detail of data files and formats. A word document providing further information is also available as part of the download. All of the .dat files of data can be viewed with a text editor such as Wordpad. 2012-2013 data may be final data from the unit owing to battery failure. The original project for this dataset was ASAC 1164, but recent data fall under the auspices of project AAS 4096.
Amery Ice Shelf - hot water drill borehole, AM06 Seabird MicroCAT CTD moorings at three depths in ocean cavity beneath the shelf - 2011-2013 data
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AM06 borehole drilled January 2010. Data being collected at annual re-visits to site. Consult Readme file for detail of data files and formats. A word document providing further information is also available as part of the download. All of the .dat files of data can be viewed with a text editor such as Wordpad. 2012-2013 data may be final data from the unit owing to battery failure. The original project for this dataset was ASAC 1164, but recent data fall under the auspices of project AAS 4096.
Amery Ice Shelf - hot water drill borehole, AM03 Seabird MicroCAT CTD moorings at three depths in ocean cavity beneath the shelf - 2011/2012 data
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AM03 borehole drilled December 2005. Data being collected at annual re-visits to site. Consult Readme file for detail of data files and formats. A word document providing further information is also available as part of the download. All of the .dat files of data can be viewed with a text editor such as Wordpad. 2011-2012 data may be final data from the unit owing to battery failure. The original project for this dataset was ASAC 1164, but recent data fall under the auspices of project AAS 4096.
Sea ice bio-optical measurements
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Field-based sampling: As part of Australian Antarctic Science project # 4298, a total number of 44 sea ice sites were sampled for bio-optical measurements along 4 transects on land-fast sea ice off Davis Station (Antarctica) during November – December 2015. Measurements included simultaneous hyperspectral down-welling (ice surface) irradiance (triplicate) and under-ice radiance (triplicate) measurements (320 – 900 nm, 3.3 nm resolution) with a TriOS ACC and Trios ARC radiometer, respectively. The radiance measurements were conducted with the TriOS ARC radiometer mounted onto an L-shaped arm (for deployment details see Melbourne-Thomas et al. 2015). Subsequently, snow thickness was measured with a ruler and an ice core was collected directly above the radiometer location. Sea-ice freeboard (tape measure) and ice thickness (ice core length) were also recorded. Ice cores (9 cm internal diameter) were cut into sections, and these were melted in the dark at +4 degrees C, filtered onto GFF filters and then used to measure ice algal pigment content (using High Performance Liquid Chromatography (HPLC) and spectral ice algal absorption coefficients (ap, ad, aph) for entire vertical profiles or for the lower-most 0.1 m of ice cores. The location of the sampling grid had its origin (x=0, y=0) at GPS position: -68.568904, 77.945439. Transects (128m – 512 m in length) started at x=60, x=70, x=80 and x=90 m and were sampled at y-positions of 0m, 0.5m, 1m, 2m, 4m, 8m, 16m, 32m, 64m, 128m, (256m, and 512m) on 19/11/2015, 23/11/2015, 29/11/2015 and 02/12/2015, respectively. Analysis of ice algal chlorophyll a concentration: For pigment analysis, 0.25 to 1.0 litres of melted ice core subsamples were passed through 25 mm diameter glass-fiber (Whatman GF/F) filters. The filters were then frozen and stored below −80 degrees C prior to analysis using HPLC. Samples were extracted over 15 to 18 hours in acetone before analysis by HPLC using a modified C8 column and binary gradient system with an elevated column temperature [Van Heukelem and Thomas, 2001]. Pigments were identified by retention time and absorption spectra from a photo-diode array (PDA) detector, and concentrations were determined from commercial and international standards (Sigma; DHI, Denmark). Analysis of particulate (algal and non-algal) absorption: The optical density (OD) spectra of the particulate material on these filters (see section above) were measured over the 350 to 750 nm spectral range in 0.9 nm increments, using a Cintra 404 UV/VIS dual-beam spectrophotometer equipped with an integrating sphere. The pigments on the sample filter were then extracted using the method of Kishino et al. [1985]'s method to determine the OD of the non-algal particles in a second scan. The OD due to ice algae was then obtained by calculating the difference between the optical density of the total particulate and non-algal fractions. The OD measurements were converted to absorption spectra using blank filter measurements, and by first normalizing the scans to zero at 750 nm and then correcting for the path length amplification using the coefficients of Mitchell [1990]. A detailed description of the method is given in Clementson et al. [2001], and followed SeaWiFS protocols [Muller et al., 2003]. An exponential function was fitted to all spectra of non-algal particulate material: ad(λ) = ad(350 nm) exp[−S(λ − 350 nm)] + b, (1) where ad(λ) is the residual absorption coefficient over the wavelength (λ) range 350 to 750 nm of the particles after methanol extraction, also referred to as absorption of detritus [m−1] although this may include absorption of non-extractable pigments and heterotrophic protists. A non-linear least-squares technique was used to fit Equation 1 to the untransformed data, where S and b are empirically-determined constants. The inclusion of an offset b allows for any baseline correction. In some samples, pigment extraction was incomplete, leaving small residual peaks in
Sea ice micro-zooplankton in ice cores and the water column (LOPC) observed during the SIPEX II voyage of the Aurora Australis, 2012
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This data set includes abundance and distribution of sea ice and water column micro-invertebrates. Data was collected form 8 stations over the course of the SIPEX 2 voyage. The data for this project consists of 2 separate collection regimes: Ice cores - a number of ice were taken at stations 1-6, using a 15cm corer, they were sectioned and dissolved in filtered seawater before being fixed in formalin. At Station 6 sufficient biomass was present in the bottom 10cm of some cores to allow microscopic separation of copepod species, which were then frozen for stable isotope analysis (SIA). Lazer optical plankton counter (LOPC) was deployed at stations 2 to 7 either from ice holes (IH) or from the trawl Deck (TD) to depths of 60m or 100m. These deployments were made throughout the day where possible and were accompanied by a 100um plankton net . Each deployment consisted of 2 drops for both the LOPC and the net. Collected plankton were filtered onto 50um mesh and backwashed into vials before being fixed in 5% formalin. All LOPC files .bin will require LOPC program manufactured by ODIM Rolls Royce Nova Scotia. These files are read to format .dat which maybe opened as a .txt file
Large scale air-borne sea ice thickness measurements
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Data from ASAC project 3030. Public summary for the project: This project will measure the sea ice thickness off East Antarctica, over spatial scales up to hundreds of kilometers. Sea ice is a likely sensitive indicator of climate variations and change. No large scale sea ice thickness measurements exist in the Antarctic. An estimation of trends of change in Antarctic sea ice thickness and volume is therefore not currently possible. To address this deficiency and to provide an independent data set for the validation of models and the calibration of remote-sensing data, we will conduct high accuracy air borne laser scanner measurements in the sea ice zone off East Antarctica. More information about the project can be found in lidar.pdf (which is available with the data).