The Marg (Cu-Zn-Pb-Au-Ag) volcanogenic massive sulphide deposit is hosted within metasedimentary and metavolcanic rocks of the Devonian-Mississippian Earn Group and Mississippian Keno Hill Quartzite. These rocks form part of the Selwyn Basin, an off-shelf sequence that developed at the continental margin prior to Cordilleran deformation and accretion. Geological mapping and re-analysis of drill core was completed to re-assess the deposit and property-scale economic potential. The Marg deposit is deformed by at least three generations of structures that developed during Late Jurassic to Early Cretaceous time and are geometrically correlative with regional-scale structures such as the Robert Service Thrust and the Tombstone strain zone. The Marg deposit occurs within a southeasterly plunging, complex fold structure, a significant part of which has been removed by erosion. Discovery of additional stratigraphy comparable to the Marg sequence and new sulphide occurrences within the claims underscores both property and regional exploration potential. The presence of probable rift-related volcanism and mineralization within the Selwyn Basin, and the similarities of this mineralization to that within 'suspect' terranes, has implications for both regional tectonics and exploration.

Upper Devonian and Lower Mississippian metavolcanic rocks of Yukon-Tanana Terrane in southern Finlayson Lake and Frances Lake map areas occur in three thrust sheets, locally modified by a Cretaceous normal fault. The lower thrust sheet, the Big Campbell sheet, comprises the Upper Devonian to Lower Mississippian metavolcanic stratigraphy that hosts the main volcanichosted massive sulphide (VHMS) deposits of the district. Metavolcanic rocks in the middle thrust sheet, the Money Creek sheet, include the Upper Devonian Waters Creek and Early Mississippian Tuchitua River formations. The former comprises primarily felsic metavolcanic rocks and carbonaceous phyllite and is extensively intruded by sheets of comagmatic porphyry. The latter comprises primarily intermediate metavolcanic, volcaniclastic and epiclastic rocks. The upper thrust sheet, the Cleaver Lake sheet, is in part made up of Late Devonian calc-alkaline basalt and rhyolite, the Cleaver Lake formation, and comagmatic felsic to ultramafic plutonic rocks. Of these, the Waters Creek formation and the formations in the Big Campbell sheet have the highest potential to host VHMS deposits.

Regional-scale thrust faults in the Klondike District separate major lithologic units that include medium-grade metamorphic rocks of the Upper Permian Klondike Schist and middle to late Paleozoic Finlayson (Nasina) assemblage, as well as relatively low-grade greenstone and ultramafic rocks of the Slide Mountain terrane. These units were emplaced in the Jurassic as a series of kilometre-scale stacked thrust slices that are locally separated by additional ultramafic slices. A distinctive set of post-metamorphic compressional structures related to thrusting, particularly a set of ductile recumbent folds and associated spaced cleavage, is preserved in all thrust slices and is well developed near bounding faults. In carbonaceous units within the Klondike Schist, spatially associated with some thrusts, carbonaceous material is locally concentrated along the thrust-related spaced cleavage. Thrust-related fabrics are overprinted by kink-folding that locally affects the Finlayson assemblage, but is mainly developed in Klondike Schist. Gold-bearing veins appear confined to Klondike Schist and were emplaced in local sites of extension controlled principally by axial surfaces of these kink folds.

The central Pelly Mountains in southeastern Yukon Territory consist of imbricate thrust sheets, which have undergone syn and post-thrusting deformation and metamorphism. The local geology is further complicated by intrusion of Upper Cretaceous batholiths, and by strike-slip faulting related to the Tintina Fault, a major northwest-trending transcurrent fault of uppermost Cretaceous or early Tertiary age. This faulting disrupts the northeast edge of the study area. Upper Devonian and Mississippian strata are present in at least two of the thrust sheets, but the Mississippian volcanic rocks occur in only one of them. The volcanic rocks consist of volcaniclastic material with minor interbedded flows, and were deposited in a submarine environment. Several coeval and cogenetic syenite and trachyte domes and small stocks are the remains of vent areas. Although the volcanic rocks are all highly altered and show evidence of widespread chemical mobility, trace element data indicate that the rocks are meta-luminous trachytes, most closely resembling peralkaline volcanics generated in extensional environments. This suggestion of a predominantly extensional tectonic setting in mid-Mississippian time in the Pelly Mountains is consistent with recent tectonic syntheses for the area. Stratabound and stratiform massive base metal sulphide deposits that occur within the Mississippian volcanic sequence are similar in many respects to the Kuroko-type volcanogenic massive sulphide deposits of Japan. The Pelly Mountains deposits, however, are among the first known occurrences in the world of Kuroko-type mineralization in a rift environment. A copy of this thesis is available at the EMR library – QE195 M67 1979. This thesis is available online at http://hdl.handle.net/2429/22257.

The Yukon-Tanana Terrane (YTT) in the Finlayson Lake region (FLR), southeastern Yukon, Canada is host to five volcanic-hosted massive sulphide (VHMS) deposits (total -34 Mt) that have been discovered since the mid-1990's. In this thesis, field, lithogeochemical and Nd isotopic data are presented for felsic and mafic igneous rocks in the FLR to understand the tectonic setting, style of magmatism, and their relationships to VHMS mineralization. All rocks in the FLR were built upon a continental (or continent-derived) substrate of pre-Mississippian (>365 Ma) age. The Fire Lake unit (FLU) reflects Devonian-Mississippian (-365-360 Ma) arc and back-arc magmatism built upon a composite basement of oceanic and continental (or continent-derived) crust above an east-dipping subduction zone. Models proposed herein for the magmatic and tectonic evolution of FLU include: 1) arc magmatism punctuated by back-arc basin generation; 2) ridge propagation into an evolving arc with subsequent evolution to back-arc magmatism; and/or 3) ridge-subduction (slab-window) with eventual back-arc basin magmatism. The Kudz Ze Kayah (KZK) unit overlies the FLU and consists predominantly of crustally derived Devonian-Mississippian (-360-356 Ma) felsic volcanic and high-level subvolcanic rocks and variably carbonaceous sedimentary rocks; the latter are crosscut and overlain by alkalic mafic rocks. The high field strength element (HFSE)-enriched (A-type) felsic rocks and alkalic mafic rocks in the KZK unit are inferred to represent magmatism within an ensialic back-arc basin upon evolved crust. The Wolverine succession (WS) unconformably overlies the KZK unit and consists of a lower succession of felsic volcanic and subvolcanic rocks with carbonaceous sedimentary rocks; the upper portion of the succession, above the Wolverine VHMS deposit, consists predominantly of aphyric rhyolitic rocks that are overlain basalt flows. Felsic rocks ofthe WS are broadly similar to those in the KZK unit and represent ensialic back-arc basin magmatism. However, the succession is younger (-356-346 Ma), and post-dates a period of uplift, deformation, and erosion prior to commencement of back-arc magmatism. Back-arc spreading eventually evolved to true seafloor spreading within the WS. Massive sulphide deposits in the FLR are preferentially associated with rocks indicative of high temperature magmatism (e.g., boninites, A-type felsic rocks) and extensional tectonic activity (e.g., back-arc rifting and spreading).

The Wolverine polymetallic volcanic-hosted massive sulphide deposit occurs in a highly deformed but coherent stratigraphic succession of early Mississippian to early Permian metavolcanic and metasedimentary rocks of the Yukon-Tanana Terrane. The deposit is part of the emerging Finlayson Lake volcanic-hosted massive sulphide district and contains a geological resource of 6,237,000 tonnes grading 12.66% zinc, 1.33% copper, 1.55% lead, 370.9 g/t silver and 1.76 g/t gold. Local stratigraphy consists of four major units including (from oldest to youngest): (1) quartz-and feldspar-phyric volcaniclastic, carbonaceous sedimentary and porphyritic intrusive rocks; (2) interbedded argillite, aphyric rhyolite and magnetite-carbonate-pyrite exhalite; (3) fragmental rhyolite; and (4) interbedded carbonaceous argillite, greywacke, basalt and rhyolite. The mineralization consists of pyrite and sphalerite, with lesser pyrrhotite, chalcopyrite, galena, tetrahedrite-tennantite and arsenopyrite. Mineralization occurs as massive stratiform, massive replacement and sulphide stringer veins. Sulphides are typically massive, fine-grained, layered and locally brecciated. Styles of hydrothermal alteration identified in the host rocks include proximal silicification and more distal chloritization, sericitization and, in places, carbonatization. Future research will be focussed on identifying the salient physico-chemical controls on the mineralization process and their implications for volcanic-hosted massive sulphide exploration in the district and elsewhere.

Although deformed and metamorphosed, the strata hosting volcanogenic massive sulphide deposits in the Finlayson Lake district retain characteristics that suggest the influence of syn-depositional faults near the deposits. The Fyre Lake deposit occurs within a mafic schist unit near where notable changes in thickness, rock type and amount of comagmatic metaplutonic rocks occur. These changes occur across a north-northwest-striking corridor along which deposits and prospects in the overlying felsic metavolcanic schist are distributed (including Kudz Ze Kayah). Syn-volcanic, syn-mineralization faulting would explain the association of these deposits with the observed changes in host rock characteristics. Using similar arguments, syn-mineralization faults have been inferred on the Hat Trick property southwest of Fire Lake, as well as in Pennsylvanian and Permian rocks of the Campbell Range succession. Finally, stratigraphic differences between coeval rocks in the hanging wall and footwall of the Money Creek thrust imply that the thrust may have re-activated a syn-depositional structure. The regions of hanging wall and footwall cut-offs of the Money Creek thrust would therefore be considered as highly prospective for massive sulphide deposits.

During the 2000 field season, a project was initiated to study the geology, geochemistry and alteration characteristics of high-level subvolcanic porphyritic intrusions associated with the Wolverine volcanic-hosted massive sulphide deposit in the Finlayson Lake district, Yukon. Subvolcanic porphyritic intrusions within the Wolverine deposit are located approximately 10-20 m beneath exhalative sulphide bodies or iron-formation in four zones (Wolverine/Lynx, Fisher, Sable and Puck). Most intrusions are K-feldspar porphyritic (Fisher and Wolverine/Lynx Zones); however, a few are quartz and K-feldspar porphyritic (Puck and Sable zones). Feldspar-porphyritic intrusions consist of euhedral to subhedral grains of K-feldspar in a grey fine-grained matrix. Quartz-feldspar porphyritic intrusions contain slightly smaller feldspar crystals and blue to black glassy quartz eyes set in a fine-grained matrix. Most of the intrusions have non-peperitic upper margins with carbonaceous argillite (Wolverine/Lynx, Fisher, Puck). Some of the quartz- feldspar porphyritic intrusions are in contact with fine-grained volcaniclastic rocks along their upper margins (Sable); both types of intrusions have lower contacts with fine-grained volcaniclastic sedimentary rocks. These intrusions are, for the most part, unaltered and have only minor sericite-silica ±chlorite ±pyrite alteration and small mm-to cm-scale veinlets of quartz-sericite ±chlorite ±pyrite ± sphalerite. This suggests a pre-to syn-mineralization timing for the emplacement of the intrusions. The contribution of these intrusions to the heat and metal budget of the Wolverine deposit is the focus of ongoing research.

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