Gold-sulphide enrichment processes in mesothermal veins of the Sixtymile River area, Yukon Territory, Canada
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The upper Sixtymile River area is located approximately 128 km west of Dawson City, Yukon. Lithology in this area consists of Precambrian to Paleozoic metamorphic rocks, Paleozoic ultramafic rocks, Middle Jurassic pegmatite and aplite dykes, Late Cretaceous porphyritic dykes and volcanic rocks with intercalated sedimentary rocks, Quaternary alkaline basaltic dykes and Quaternary alluvial sediments. Gold bearing, mesothermal quartz-(carbonate)-sulphide veins which trend NNE-SSW are hosted by metamorphic rocks north and south of Sixtymile River. The mesothermal quartz-(carbonate)-sulphide veins are surrounded by successive envelopes of sericitic, K-feldspar and propylitic alteration. Two stages of vein mineralization are recognized in the northern part of the area, and three stages are recognized in the south part. In the northern veins, pyrite, arsenopyrite, pyrrhotite and quartz are intergrown and formed first. These minerals are fractured and healed by second stage minerals, which include galena, sphalerite, chalcopyrite, pyrite, carbonate and minor quartz. Stage I mineralization in the southern veins is represented by quartz, and pyrite containing inclusions of other sulphides. Stage II is the main stage of precious metal enrichment, represented by arsenopyrite and galena which contain tetrahedrite, miagyrite and polybasite exsolutions. Stage I and II minerals are tectonically fractured, and healed by pyrite, sphalerite, chalcopyrite, freibergite and quartz of stage III. In both vein systems, gold enrichment is associated with arsenopyrite and silver enrichment is associated with galena. The evolution of hydrothermal fluids in the northern area is characterized by decreasing temperature (330°C to 280°C), salinity (12.8% wt.-% to 6 wt.-% NaCI equiv.), oxygen activity (log a(O2) = -30 to log a(O2) = -35), and sulphur activity (log a(S2) = -10 to log a(S2) = -12), as well as a slight increase in pH range (from >3.1 - <5.2 to >3.3 - <5.4). In the southern vein system the fluid evolution characterized by a decrease in temperature (330°C to 150°C), salinity (18.3 wt.-% to 10 wt.-% NaCI equiv.), oxygen activity (log a(O2) = -29 to log a (02) = - 52), and sulphur activity (log a(S2) = -9 to log a(S2) = -18, as well as a slight increase in pH range (>3.2 - <5.3 to >4.1 - <5.9). The following conclusions can be drawn about the fluid composition and mineral enrichment process in the fossil geothermal system of the Sixtymile River area. Deep seated fluids which circulated in the metamorphic rocks were characterized by high temperatures (above 300°C), high salinities (about 18 wt.-% NaCI equiv.) and pH values between 3.1 and 5.2. These fluids are similar to alkaline chloride fluids of active geothermal systems. Arsenic was transported as H3AsO3°-complex, gold as Au(HS)2- and lead, zinc, iron, copper as MeCl2° complexes. The first stage mineralization resulted from reaction of this deep-seated fluid with the wall rock. Second and third stage mineralization is believed to result from the mixing of two fluids with different physico-chemical characteristics.
Upper Paleozoic strata with potential for massive sulphide mineralization, northwestern Lansing map area (105 N), Yukon
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Northwestern Lansing map area, 120 km east of Mayo, lacks known mineral occurrences yet contains upper Paleozoic stratigraphic units similar to those at volcanic-hosted and sedimentary exhalative deposits such as Marg and Macmillan Pass. Pyritic and locally baritic Earn Group and (previously unmapped) younger strata underlie most of the area. The sedimentary rocks are cleaved and folded but less strained than equivalent rocks in adjacent Mayo map area, and most contain abundant iron sulphide laminae, nodules, and replacements. A muscovite granite intrudes the grey-green phyllite. The Robert Service Thrust at the southern boundary of the Upper Paleozoic units, appears offset by steep, northwest-trending faults.
Petrology and Tectonic Setting of Felsic and Mafic Volcanic and Intrusive Rocks in the Finlayson Lake Volcanic-hosted Massive Sulphide (VHMS) District, Yukon, Canada: A Record of mid-paleozoic Arc and Back-arc Magmatism and Metallogeny
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The Yukon-Tanana Terrane (YTT) in the Finlayson Lake region (FLR), southeastern Yukon, Canada is host to five volcanic-hosted massive sulphide (VHMS) deposits (total -34 Mt) that have been discovered since the mid-1990's. In this thesis, field, lithogeochemical and Nd isotopic data are presented for felsic and mafic igneous rocks in the FLR to understand the tectonic setting, style of magmatism, and their relationships to VHMS mineralization. All rocks in the FLR were built upon a continental (or continent-derived) substrate of pre-Mississippian (>365 Ma) age. The Fire Lake unit (FLU) reflects Devonian-Mississippian (-365-360 Ma) arc and back-arc magmatism built upon a composite basement of oceanic and continental (or continent-derived) crust above an east-dipping subduction zone. Models proposed herein for the magmatic and tectonic evolution of FLU include: 1) arc magmatism punctuated by back-arc basin generation; 2) ridge propagation into an evolving arc with subsequent evolution to back-arc magmatism; and/or 3) ridge-subduction (slab-window) with eventual back-arc basin magmatism. The Kudz Ze Kayah (KZK) unit overlies the FLU and consists predominantly of crustally derived Devonian-Mississippian (-360-356 Ma) felsic volcanic and high-level subvolcanic rocks and variably carbonaceous sedimentary rocks; the latter are crosscut and overlain by alkalic mafic rocks. The high field strength element (HFSE)-enriched (A-type) felsic rocks and alkalic mafic rocks in the KZK unit are inferred to represent magmatism within an ensialic back-arc basin upon evolved crust. The Wolverine succession (WS) unconformably overlies the KZK unit and consists of a lower succession of felsic volcanic and subvolcanic rocks with carbonaceous sedimentary rocks; the upper portion of the succession, above the Wolverine VHMS deposit, consists predominantly of aphyric rhyolitic rocks that are overlain basalt flows. Felsic rocks ofthe WS are broadly similar to those in the KZK unit and represent ensialic back-arc basin magmatism. However, the succession is younger (-356-346 Ma), and post-dates a period of uplift, deformation, and erosion prior to commencement of back-arc magmatism. Back-arc spreading eventually evolved to true seafloor spreading within the WS. Massive sulphide deposits in the FLR are preferentially associated with rocks indicative of high temperature magmatism (e.g., boninites, A-type felsic rocks) and extensional tectonic activity (e.g., back-arc rifting and spreading).
Gold and sulphide mineralization in the Hunker Creek area, Yukon Territory, Canada
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The Hunker Creek area is located 30 km southeast of Dawson City, Yukon. Gold and sulphide-bearing quartz veins (MINFILE 115O 067, 068) crosscut metamorphic rocks of the Klondike Schist. The veins are enclosed by envelopes of sericitic (inner) and propylitic (outer) alteration. Locally, carbonatization occurs between propylitized and sericitized rocks. Three stages of vein mineralization can be distinguished:: (1) quartz, carbonates, gold, arsenopyrite, pyrite, pyrrhotite, chalcopyrite, and galena; (II) quartz, carbonates, chalcopyrite, sphalerite, tetrahedrite, freibergite, polybasite, 'polyargyrite', argentite, pyrostilbnite and galena; (III) quartz and gold. Fluid inclusion data indicate that stage I minerals precipitated from hydrothermal solutions containing CO2. Homogenization temperatures range from 260° to 390°C. Stage II aqueous fluid inclusions homogenize between 190° and 260°C. Stage III inclusions homogenize between 120° and 210°C. Salinities of the three stages range from 0 to 7.2 wt-% NaCl equiv. and show no significant changes with time. It is suggested that stage I mineralization was initiated by unmixing of an original single-phase H2O and CO2 bearing fluid, and that subsequent hydrothermal evolution was controlled mainly by decreasing temperature.
Geology and mineralization of the AurMac metasediment-hosted gold deposits, central Yukon (NTS 105M/13)
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The AurMac property, located 35 km north of Mayo in central Yukon, includes two metasedimentary rock-hosted gold deposits: the 6158 koz Au Powerline deposit and the 845 koz Au Airstrip deposit. Mineralization at the Powerline and Airstrip deposits is characterized by gold in sheeted quartz veins and mineralized skarn horizons, respectively. The AurMac deposits straddle the Robert Service thrust fault whereby the Powerline deposit is hosted in the Late Proterozoic to Cambrian Hyland Group hanging wall, and the Airstrip deposit is hosted in the Mississippian Sourdough Hill Member of the Keno Hill Quartzite footwall. Host rocks comprise siliciclastic metasedimentary rocks, variably calc-silicate–altered calcareous metasedimentary rocks and magmatic rocks. Magmatic rocks in the Powerline zone consist of foliated mafic horizons that are geochemically similar to Cambro-Ordovician magmatic rocks found in Hyland Group metasedimentary rocks in the McQuesten, Mayo, Clark Lakes and Hart River map areas. In the Airstrip zone, magmatic rocks include a steeply south-dipping, unfoliated, aplite dike. Evidence for intrusion-related gold mineralization at AurMac includes sheeted vein and skarn mineralization similar to the intrusionhosted, intrusion-related gold deposits at Dublin Gulch, as well as the presence of metamorphic porphyroblast assemblages that suggest contact metamorphism. These findings suggest potential for further discovery of mineralized intrusion-hosted zones on the AurMac property and sedimenthosted, intrusion-related gold deposits elsewhere in the region.
Geology of the Main Zone at Mt. Skukum, Wheaton River area, southern Yukon
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Gold mineralization at the Mt. Skukum deposit occurs in nearly vertical quartz-carbonate veins which crosscut flat-lying andesites with a NNE trend. The mineralized veins represent the second stage of a two stage hydrothermal system, the first of which resulted in emplacement of thin chalcedonic veinlets. These two stages of veins are probably indicative of an evolving hydrothermal fluid rather than being representative of two separate events. Vein emplacement is one of the latest of a series of events which began with volcanism, producing felsic and andesitic volcanic rocks which overlie basement in this area. Subsequent periods of tectonism produced large faults along which rhyolitic dykes were emplaced. Continued tectonism resulted in reactivation of old faults along which andesitic and dacitic dykes were injected, crosscutting rhyolite dykes in many cases. As volcanic activity waned, the faults remained active, leaving zones of high permeability which acted as conduits for the still active hydrothermal circulation. Veins appear to have been emplaced at low temperature in a circulating hydrothermal system driven by a heat source at depth associated with dykes present in the area. Circulating hydrothermal fluids may have leached gold from the surrounding andesitic volcanics during propylitization. Permeability may have been controlled by faulting, brecciated flow tops and bottoms, and lapilli tuff horizons. Gold was precipitated in highly permeable conduits, such as the Main Fault Zone and breccia bodies.
Nickel-Copper-Sulphide Deposits in Kluane Ranges, Yukon (Parts of 115F, 115G)
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A sequence of Permo-Triassic rocks within a 260 square kilometre part of the Kluane Ranges, southwestern Yukon, consists of Lower Permian volcaniclastic and sedimentary rocks, disconformably overlain by upper Triassic amygdaloidal volcanic rocks. Mafic to ultramafic rocks occur within the upper part of the Permian section and in the Triassic flows. Folding and faulting of this sequence is intense. The ultramafic rocks are peridotite-dunite complexes in the form of sills. Some gabbroic bodies have intruded along sill boundaries, but most are separate sills or dykes. Nowhere have they been found cutting rocks younger than the upper Triassic volcanics. Ni-Cu mineralization is spatially associated with the gabbros and peridotites. Dunite portions of ultramafic complexes are barren. Sulphide minerals include pyrrhotite, pentlandite and chalcopyrite, locally with pyrite, sphalerite and galena. Occurrences are classified as follows:: 1. Massive to stringer within country rock adjacent to gabbro intruding peridotite. 2. Massive to heavily disseminated at the country rock contact of gabbro intruding peridotite. 3. A) Heavily disseminated to nearly massive within gabbro intruding peridotite. B) Disseminated within separate gabbroic bodies. 4. Very weakly disseminated within peridotite. The mineralized gabbro-ultramafic intrusions are spatially related to the Triassic volcanic flows. The mafic and ultramafic rocks, their Ni-Cu deposits, and volcanic flows are believed to be related genetically. This report is accompanied by five geological maps as follows:: 1) Arch Creek (1::4760 scale; NTS 115 G/5 northeast); 2) Wellgreen area (1::4800 scale; NTS 115 G/5 northeast); 3) Linda Creek (1::2380 scale; NTS 115 G/6 northwest); 4) White River (1::4760 scale; NTS 115 F/15 northeast); and 5) Quill Creek (1::80 000; 115 G/5,6 north and 115 G/11,12 south).
Paleozoic stratigraphy, tectonics and metallogeny of the Pelly Mountains, Quiet Lake and Finlayson Lake map areas (NTS 105F and G), central Yukon: Project outline and preliminary field results
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Paleozoic rocks of the Pelly Mountains, central Yukon, preserve greater than 150 m.y. of sedimentation, magmatism and base-metal mineralization. To identify secular trends in regional tectonics and metallogeny, a multi-year project on the stratigraphy of the Pelly Mountains in the Quiet Lake (105F) and Finlayson Lake (105G) map areas was initiated. Field studies during summer 2015 focused on two stratigraphic intervals: (1) mafic volcanic, volcaniclastic and clastic rock successions assigned to the Cambrian-Ordovician Cloutier and Groundhog formations (Kechika group); and (2) felsic volcanic, volcaniclastic and clastic rock successions assigned to the Devonian-Mississippian Black Slate and Felsic Volcanic formations (Seagull group). Cambrian-Ordovician strata were deposited in a marine environment characterized by episodic mafic volcanism and extensional tectonism. Devonian-Mississippian strata record the transition from an extensional turbidite basin to a metalliferous volcanic rift basin, and resemble key rock assemblages of the Selwyn basin (Earn Group) and Yukon-Tanana terrane (Grass Lakes and Wolverine Lake groups).
Geology and geochemistry of the Clear Creek gold occurrences, Tombstone gold belt, central Yukon Territory
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Auriferous sheeted quartz veins and silicified shear zones occur along the margins and within adjacent hornfels zones of mid-Cretaceous Tombstone intrusions near the head of Clear Creek in the central Yukon. The lodes are the source for more than 120,000 ounces of downstream placer gold production. These lodes contain variable amounts pyrrhotite, pyrite, and arsenopyrite, with less abundant scheelite - alkali-feldspar, muscovite, biotite and tourmaline are common gangue phases. Grab samples of mineralization often contain gold grades in excess of 1 ounce per ton. Gold-to-silver ratios vary most commonly from 1:1 to 5:1. Gold-rich quartz veins cut all stocks, adjacent hornfels and associated lamprophyre dykes commonly contain greater than 1% arsenic. Bismuth, and less consistently tungsten and stibnite, characterize many of the most highly mineralized veins within and surrounding the stocks. Quartz veins along the intrusive-metasedimentary rock contact around the Pukelman stock are also enriched in lead and silver. R-mode factor analysis of multi-element geochemical data for 111 gold- and sulphide-bearing rock samples indicates that there are two geochemically distinct metal suites in the Clear Creek occurrences. The first is characterized by As-Au-Bi ± Sb, Te ore-related mineral association, which is typical of many intrusion-related deposits in the Tombstone gold belt. Less consistently, anomalous concentrations of Ag, Co, Cu, Fe, and Mo occur within these auriferous rocks. The second metal factor is defined by Ag-Bi-Pb ± As, Au and Te. It characterizes metalliferous vein samples that have uncommonly low Au: Ag ratios and may represent a second hydrothermal episode. Tungsten shows little consistent correlation with the metalliferous veins in either element suite.