This dataset contains carbon dioxide (CO2) system data collected by scientists from the U.S. Geological Survey (USGS) St. Petersburg Coastal and Marine Science Center (SPCMSC) to investigate the effects of Mercuric chloride (HgCl2) on low salinity, organic-rich estuarine water samples acquired from the Tampa Bay estuary located in west central Florida. Discrete water samples were collected using two, 30-liter (30L) Niskin bottles to capture surficial waters from the lower Hillsborough River. Filtered water samples collected from one Niskin bottle were "poisoned" with HgCl2 (according to best practices (Dickson and others, 2007), while filtered water samples collected from the second Niskin were left "as is" (unpoisoned) to act as the experimental control. Water samples were analyzed incrementally over a period of three months at the USGS Carbon Analytical Laboratory in St. Petersburg, Florida. This dataset contains the elapsed time experimental results of CO2 system parameters including water temperature (Celsius, C), salinity, pHT (pH on the total scale), total alkalinity (AT, micromoles/kg), and total dissolved inorganic carbon (CT, micromoles/kg). For further information regarding data collection and/or processing methods, please refer to the associated journal publication (Moore and others, 2023), which is based on a thesis publication by Moore and others (2021).

This dataset contains carbon dioxide (CO2) system data collected by scientists from the U.S. Geological Survey (USGS) St. Petersburg Coastal and Marine Science Center (SPCMSC) to investigate the effects of Mercuric chloride (HgCl2) on low salinity, organic-rich estuarine water samples acquired from the Tampa Bay estuary located in west central Florida. Discrete water samples were collected using two, 30-liter (30L) Niskin bottles to capture surficial waters from the lower Hillsborough River. Filtered water samples collected from one Niskin bottle were "poisoned" with HgCl2 (according to best practices (Dickson and others, 2007), while filtered water samples collected from the second Niskin were left "as is" (unpoisoned) to act as the experimental control. Water samples were analyzed incrementally over a period of three months at the USGS Carbon Analytical Laboratory in St. Petersburg, Florida. This dataset contains the elapsed time experimental results of CO2 system parameters including water temperature (Celsius, C), salinity, pHT (pH on the total scale), total alkalinity (AT, micromoles/kg), and total dissolved inorganic carbon (CT, micromoles/kg). For further information regarding data collection and/or processing methods, please refer to the associated journal publication (Moore and others, 2023), which is based on a thesis publication by Moore and others (2021).

The United States Geological Survey (USGS) is studying the effects of climate change on ocean acidification within the Gulf of Mexico; dealing specifically with the effect of ocean acidification on marine organisms and habitats. To investigate this, the USGS participated in cruises on the West Florida Shelf and northern Gulf of Mexico regions aboard the research vessel (R/V) Weatherbird II or Bellows, ships of opportunity led by Dr. Kendra Daly, of the University of South Florida (USF) in July and August, 2013. Cruises left from and returned to Saint Petersburg, Florida, but followed different routes. The USGS collected geochemical data pertaining to pH, dissolved inorganic carbon (DIC), total carbon dioxide (TCO2), and total alkalinity (TA) in discrete samples at various depths from predetermined stations. Discrete surface samples were also taken, while in transit, during both cruises.

The United States Geological Survey (USGS) is conducting a study on the effects of climate change on ocean acidification within the Gulf of Mexico; dealing specifically with the effect of ocean acidification on marine organisms and habitats. To investigate this, the USGS participated in cruises in the West Florida Shelf and northern Gulf of Mexico regions aboard the R/V Weatherbird II, a ship of opportunity lead by Dr. Kendra Daly, of the University of South Florida (USF). This cruise occurred February 17-23, 2011, leaving from and returned to Saint Petersburg, Florida. The USGS collected data pertaining to pH, dissolved inorganic carbon (DIC), and total alkalinity in discrete samples. Seventy-one underway discrete samples were collected approximately hourly over a span of 1628 kilometer (km) track line, additionally 34 samples were taken at 10 stations. Flow-through conductivity-temperature-depth (CTD) data were collected, which includes temperature, salinity, and pH. Corroborating the USGS data are the vertical CTD profiles collected by USF, using the following sensors: CTD, oxygen, chlorophyll fluorescence, optical backscatter, and transmissometer. Additionally, discrete depth samples for nutrients, chlorophyll, and particulate organic carbon/nitrogen were collected.

The United States Geological Survey (USGS) is conducting a study on the effects of climate change on ocean acidification within the Gulf of Mexico; dealing specifically with the effect of ocean acidification on marine organisms and habitats. To investigate this, the USGS participated in cruises in the West Florida Shelf and northern Gulf of Mexico regions aboard the R/V Weatherbird II, a ship of opportunity lead by Dr. Kendra Daly, of the University of South Florida (USF). This cruise occurred February 17-23, 2011, leaving from and returned to Saint Petersburg, Florida. The USGS collected data pertaining to pH, dissolved inorganic carbon (DIC), and total alkalinity in discrete samples. Seventy-one underway discrete samples were collected approximately hourly over a span of 1628 kilometer (km) track line, additionally 34 samples were taken at 10 stations. Flow-through conductivity-temperature-depth (CTD) data were collected, which includes temperature, salinity, and pH. Corroborating the USGS data are the vertical CTD profiles collected by USF, using the following sensors: CTD, oxygen, chlorophyll fluorescence, optical backscatter, and transmissometer. Additionally, discrete depth samples for nutrients, chlorophyll, and particulate organic carbon/nitrogen were collected.

The United States Geological Survey (USGS) is conducting a study on the effects of climate change on ocean acidification within the Gulf of Mexico; dealing specifically with the effect of ocean acidification on marine organisms and habitats. To investigate this, the USGS participated in cruises in the West Florida Shelf and northern Gulf of Mexico regions aboard the R/V Weatherbird II, a ship of opportunity lead by Dr. Kendra Daly, of the University of South Florida (USF). This cruise occurred May 03 - 09, 2011, leaving from and returned to Saint Petersburg, Florida. The USGS collected data pertaining to pH, dissolved inorganic carbon (DIC), and total alkalinity in discrete samples. Thirty-four underway discrete samples were collected approximately hourly over a span of 1632 kilometer (km) track line, additionally 44 discrete samples were taken at four stations, these were taken at various depths. Flow-through conductivity-temperature-depth (CTD) data were collected, which includes temperature, salinity, and pH. Corroborating the USGS data are the vertical CTD profiles collected by USF, using the following sensors: CTD, oxygen, chlorophyll fluorescence, optical backscatter, and transmissometer. Additionally, discrete depth samples for nutrients, chlorophyll, and particulate organic carbon/nitrogen were collected.

The United States Geological Survey (USGS) is conducting a study on the effects of climate change on ocean acidification within the Gulf of Mexico; dealing specifically with the effect of ocean acidification on marine organisms and habitats. To investigate this, the USGS participated in cruises in the West Florida Shelf and northern Gulf of Mexico regions aboard the R/V Weatherbird II, a ship of opportunity lead by Dr. Kendra Daly, of the University of South Florida (USF). This cruise occurred June 25 - 30, 2011, leaving from and returned to Saint Petersburg, Florida. The USGS collected data pertaining to pH, dissolved inorganic carbon (DIC), and total alkalinity in discrete samples over a span of 1632 kilometer (km) track line, additionally 36 discrete samples were taken at ten stations, these were taken at various depths. Flow-through conductivity-temperature-depth (CTD) data were collected, which includes temperature, salinity, and pH. Corroborating the USGS data are the vertical CTD profiles collected by USF, using the following sensors: CTD, oxygen, chlorophyll fluorescence, optical backscatter, and transmissometer. Additionally, discrete depth samples for nutrients, chlorophyll, and particulate organic carbon/nitrogen were collected.

The United States Geological Survey (USGS) is conducting a study on the effects of climate change on ocean acidification within the Gulf of Mexico; dealing specifically with the effect of ocean acidification on marine organisms and habitats. To investigate this, the USGS participated in cruises in the West Florida Shelf and northern Gulf of Mexico regions aboard the R/V Weatherbird II, a ship of opportunity lead by Dr. Kendra Daly, of the University of South Florida (USF). This cruise occurred June 25-30, 2011, leaving from and returned to Saint Petersburg, Florida. The USGS collected data pertaining to pH, dissolved inorganic carbon (DIC), and total alkalinity in discrete samples. Thirty-six discrete samples were collected at ten stations. Flow-through conductivity-temperature-depth (CTD) data were collected, which includes temperature, salinity, and pH. Corroborating the USGS data are the vertical CTD profiles collected by USF, using the following sensors: CTD, oxygen, chlorophyll fluorescence, optical backscatter, and transmissometer. Additionally, discrete depth samples for nutrients, chlorophyll, and particulate organic carbon/nitrogen were collected.

The United States Geological Survey (USGS) is conducting a study on the effects of climate change on ocean acidification within the Gulf of Mexico; dealing specifically with the effect of ocean acidification on marine organisms and habitats. To investigate this, the USGS participated in cruises in the West Florida Shelf and northern Gulf of Mexico regions aboard the R/V Weatherbird II, a ship of opportunity lead by Dr. Kendra Daly, of the University of South Florida (USF). This cruise occurred June 25-30, 2011, leaving from and returned to Saint Petersburg, Florida. The USGS collected data pertaining to pH, dissolved inorganic carbon (DIC), and total alkalinity in discrete samples. Thirty-six discrete samples were collected at ten stations. Flow-through conductivity-temperature-depth (CTD) data were collected, which includes temperature, salinity, and pH. Corroborating the USGS data are the vertical CTD profiles collected by USF, using the following sensors: CTD, oxygen, chlorophyll fluorescence, optical backscatter, and transmissometer. Additionally, discrete depth samples for nutrients, chlorophyll, and particulate organic carbon/nitrogen were collected.

The United States Geological Survey (USGS) is conducting a study on the effects of climate change on ocean acidification within the Gulf of Mexico; dealing specifically with the effect of ocean acidification on marine organisms and habitats. To investigate this, the USGS participated in two cruises in the West Florida Shelf and northern Gulf of Mexico regions aboard the R/V Weatherbird II, a ship of opportunity lead by Dr. Kendra Daly, of the University of South Florida (USF). The cruises occurred September 20 - 28 and November 2 - 4, 2011. Both left from and returned to Saint Petersburg, Florida, but followed different routes (see Trackline). On both cruises the USGS collected data pertaining to pH, dissolved inorganic carbon (DIC), and total alkalinity in discrete samples. Discrete surface samples were taken during transit approximatly hourly on both cruises, 95 in September were collected over a span of 2127 km, and 7 over a trackline of 732 km line on the November cruise. Along with the surface samples, another set of samples were taken at various depths at stations; 27 in September at four stations and 15 in November at five stations. In addition to the discrete samples flow-through data was also collected on both cruises in a variety of forms. Surface CTD data was collected every five minutes which includes temperature, salinity, and pH. In addition, two more flow-through instruments were setup on both cruises that recorded pH and CO2 every 15 minutes. Corroborating the USGS data is the vertical CTD profiles collected by USF, using the following sensors: CTD, oxygen, chlorophyll fluorescence, optical backscatter, and transmissometer. Additionally, discrete depth samples for nutrients, chlorophyll, and particulate organic carbon/nitrogen were collected.