This data set includes results for hormone and pharmaceutical compounds analyzed in environmental and quality-control samples collected by the USGS National Water-Quality Assessment Project during 2013 through 2015 for a study of groundwater resources used for drinking-water supply across the United States. This data release includes: Table 1. Site information and ancillary data (including principal aquifer, rock type, well depth, groundwater age information, aridity information, and land-use information) for groundwater sites sampled for hormones and pharmaceuticals by the National Water-Quality Assessment Project, 2013-15. Table 2. Hormone and pharmaceutical results for groundwater samples collected by the National Water-Quality Assessment Project, 2013-15. Table 3. Hormone and pharmaceutical results for field related blank samples of known blank type collected by the National Water-Quality Assessment Project for groundwater, 2013-15. Table 4. Hormone and pharmaceutical results for laboratory matrix spikes and associated environmental samples collected by the National Water-Quality Assessment Project for groundwater, 2013-15. Table 5. Hormone and pharmaceutical results for replicate samples and associated environmental samples collected by the National Water-Quality Assessment Project for groundwater, 2013-15.

This data set includes results for hormone and pharmaceutical compounds analyzed from 2012 through 2016 in laboratory quality-control samples that are associated with environmental samples collected by the National Water-Quality Assessment (NAWQA) Project during 2013 through 2015 for a study of groundwater resources used for drinking-water supply across the United States. Hormone and pharmaceutical results are provided for laboratory set blanks and reagent spikes analyzed during a time period that encompasses laboratory analysis of the environmental samples collected by NAWQA. This data release includes: Table 1. Hormone results for laboratory set blanks, December 18, 2012 through March 7, 2016. Table 2. Pharmaceutical results for laboratory set blanks, December 14, 2012 through March 4, 2016. Table 3. Hormone results for laboratory reagent spikes, June 17, 2013 through December 11, 2015. Table 4. Pharmaceutical results for laboratory reagent spikes, June 18, 2013 through October 1, 2015.

This data set includes results for hormone and pharmaceutical compounds analyzed from 2012 through 2016 in laboratory quality-control samples that are associated with environmental samples collected by the National Water-Quality Assessment (NAWQA) Project during 2013 through 2015 for a study of groundwater resources used for drinking-water supply across the United States. Hormone and pharmaceutical results are provided for laboratory set blanks and reagent spikes analyzed during a time period that encompasses laboratory analysis of the environmental samples collected by NAWQA. This data release includes: Table 1. Hormone results for laboratory set blanks, December 18, 2012 through March 7, 2016. Table 2. Pharmaceutical results for laboratory set blanks, December 14, 2012 through March 4, 2016. Table 3. Hormone results for laboratory reagent spikes, June 17, 2013 through December 11, 2015. Table 4. Pharmaceutical results for laboratory reagent spikes, June 18, 2013 through October 1, 2015.

Groundwater-quality data were collected from 983 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program and are included in this report. The data were collected from six types of well networks: principal aquifer study networks, which are used to assess the quality of groundwater used for public water supply; land-use study networks, which are used to assess land-use effects on shallow groundwater quality; major aquifer study networks, which are used to assess the quality of groundwater used for domestic supply; enhanced trends networks, which are used to evaluate the time scales during which groundwater quality changes; vertical flow-path study networks, which are used to evaluate changes in groundwater quality from shallow to deeper depths; and modeling support studies, which are used to provide data to support groundwater modeling. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including major ions, nutrients, trace elements, volatile organic compounds, pesticides, radionuclides, microbiological indicators, and some special interest constituents (arsenic speciation, chromium [VI] and perchlorate). Most of the data included were collected from wells that were sampled between January 2017 and December 2019. Microbiological indicator data for networks sampled in 2016 are included in this data release. These groundwater quality networks are described in a U.S. Geological Survey Data Series report DS####, which is available at https://dx.doi.org/XXXXXX, and the results are in this data release. Data for quality-control samples collected in 2017 through 2019 also are included in this data release. Data from samples collected between 2012 and 2016 are associated with networks described in previous reports in this data series (Arnold and others, 2016a and b; 2017a and b; 2018a and b; and 2020a and b). There are 24 data tables included in this data release and they are referenced as tables 1 through 14 and appendix tables 5-11 through 5-20 in the larger work citation (see supplemental information for descriptions). Two tables summarizing well depth and open interval are included in the data series report and were derived from table 1 in this data release. A separate table named DSR_2017-19_Description_of_Data_Fields.txt describes the 405 unique fields contained in the 24 data tables.

Groundwater-quality data were collected from 983 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program and are included in this report. The data were collected from six types of well networks: principal aquifer study networks, which are used to assess the quality of groundwater used for public water supply; land-use study networks, which are used to assess land-use effects on shallow groundwater quality; major aquifer study networks, which are used to assess the quality of groundwater used for domestic supply; enhanced trends networks, which are used to evaluate the time scales during which groundwater quality changes; vertical flow-path study networks, which are used to evaluate changes in groundwater quality from shallow to deeper depths; and modeling support studies, which are used to provide data to support groundwater modeling. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including major ions, nutrients, trace elements, volatile organic compounds, pesticides, radionuclides, microbiological indicators, and some special interest constituents (arsenic speciation, chromium [VI] and perchlorate). Most of the data included were collected from wells that were sampled between January 2017 and December 2019. Microbiological indicator data for networks sampled in 2016 are included in this data release. These groundwater quality networks are described in a U.S. Geological Survey Data Series report DS####, which is available at https://dx.doi.org/XXXXXX, and the results are in this data release. Data for quality-control samples collected in 2017 through 2019 also are included in this data release. Data from samples collected between 2012 and 2016 are associated with networks described in previous reports in this data series (Arnold and others, 2016a and b; 2017a and b; 2018a and b; and 2020a and b). There are 24 data tables included in this data release and they are referenced as tables 1 through 14 and appendix tables 5-11 through 5-20 in the larger work citation (see supplemental information for descriptions). Two tables summarizing well depth and open interval are included in the data series report and were derived from table 1 in this data release. A separate table named DSR_2017-19_Description_of_Data_Fields.txt describes the 405 unique fields contained in the 24 data tables.

Groundwater samples were collected and analyzed from 782 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program and the water-quality data and quality-control data are included in this data release. The samples were collected from three types of well networks: principal aquifer study networks, which are used to assess the quality of groundwater used for public water supply; land-use study networks, which are used to assess land-use effects on shallow groundwater quality, and major aquifer study networks, which are used to assess the quality of groundwater used for domestic supply. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including nutrients, major ions, trace elements, volatile organic compounds (VOCs), pesticides, radionuclides, and microbial indicators. Data from samples collected between 2012 and 2019 are associated with networks described in a collection of data series reports and associated data releases (Arnold and others, 2016a,b, 2017a,b, 2018a,b, 2020a,b; Kingsbury and others, 2020 and 2021). This data release includes data from networks sampled in 2019 through 2022. For some networks, certain constituent group data were not completely reviewed and released by the analyzing laboratory for all network sites in time for publication of this data release. For networks with incomplete data, no data were published for the incomplete constituent group(s). Datasets excluded from this data release because of incomplete results will be included in the earliest data release published after the dataset is complete. NOTE: While previous versions are available from the author, all the records in previous versions can be found in version 3.0. First posted - December 12, 2021 (available from author) Revised - January 27, 2023 (version 2.0: available from author) Revised - November 2, 2023 (version 3.0) The compressed file (NWQP_GW_QW_DataRelease_v3.zip) contains 24 files: 23 files of groundwater-quality, quality-control data, and general information in ASCII text tab-delimited format, and one corresponding metadata file in xml format that includes descriptions of all the tables and attributes. A shapefile containing study areas for each of the sampled groundwater networks also is provided as part of this data release and is described in the metadata (Network_Boundaries_v3.zip). The files are as follows: Description_of_Data_Field_v3.txt: Information for all constituents and ancillary information found in Tables 3 through 21. Network_Reference_List_v3.txt: References used for the description of the networks sampled by the USGS NAWQA Project. Table_1_site_list_v3.txt: Information about wells that have environmental data. Table_2_parameters_v3.txt: Constituent primary uses and sources; laboratory analytical schedules and sampling period; USGS parameter codes (pcodes); comparison thresholds; and reporting levels. Table_3_qw_indicators_v3.txt: Water-quality indicators in groundwater samples collected by the USGS NAWQA Project. Table_4_nutrients_v3.txt: Nutrients and dissolved organic carbon in groundwater samples collected by the USGS NAWQA Project. Table_5_major_ions_v3.txt: Major and minor ions in groundwater samples collected by the USGS NAWQA Project. Table_6_trace_elements_v3.txt: Trace elements in groundwater samples collected by the USGS NAWQA Project. Table_7_vocs_v3.txt: Volatile organic compounds (VOCs) in groundwater samples collected by the USGS NAWQA Project. Table_8_pesticides_v3.txt: Pesticides in groundwater samples collected by the USGS NAWQA Project. Table_9_radchem_v3.txt: Radionuclides in groundwater samples collected by the USGS NAWQA Project. Table_10_micro_v3.txt: Microbiological indicators in groundwater samples collected by the USGS NAWQA Project. Table_11_qw_ind_QC_v3.txt: Water-quality indicators in groundwater replicate samples collected by the USGS NAWQA Project.

Groundwater samples were collected and analyzed from 1,015 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program and the water-quality data and quality-control data are included in this data release. The samples were collected from three types of well networks: principal aquifer study networks, which are used to assess the quality of groundwater used for public water supply; land-use study networks, which are used to assess land-use effects on shallow groundwater quality; and major aquifer study networks, which are used to assess the quality of groundwater used for domestic supply. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including nutrients, major ions, trace elements, volatile organic compounds (VOCs), pesticides, radionuclides, and microbial indicators. Data from samples collected between 2012 and 2019 are associated with networks described in a collection of data series reports and associated data releases (Arnold and others, 2016a,b, 2017a,b, 2018a,b, 2020a,b; Kingsbury and others, 2020 and 2021). This data release includes data from networks sampled in 2019 through 2023. For some networks, certain constituent group data were not completely reviewed and released by the analyzing laboratory for all network sites in time for publication of this data release. For networks with incomplete data, no data were published for the incomplete constituent group(s). Datasets excluded from this data release because of incomplete results will be included in the earliest data release published after the dataset is complete. NOTE: While previous versions are available from the author, all the records in previous versions can be found in version 4.0. First posted - December 12, 2021 (available from author) Revised - January 27, 2023 (version 2.0: available from author) Revised - November 2, 2023 (version 3.0: available from author) Revised - April 18, 2025 (version 4.0) The compressed file (NWQP_GW_QW_DataRelease_v4.zip) contains 24 files: 23 files of groundwater-quality, quality-control data, and general information in ASCII text tab-delimited format, and one corresponding metadata file in xml format that includes descriptions of all the tables and attributes. A shapefile containing study areas for each of the sampled groundwater networks also is provided in folder NWQP_GW_QW_Network_Boundaries_v4 of this data release and is described in the metadata (Network_Boundaries_v4.zip). The 23 data files are as follows: Description_of_Data_Fields_v4.txt: Information for all constituents and ancillary information found in Tables 3 through 21. Network_Reference_List_v4.txt: References used for the description of the networks sampled by the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project. Table_1_site_list_v4.txt: Information about wells that have environmental data. Table_2_parameters_v4.txt: Constituent primary uses and sources; laboratory analytical schedules and sampling period; USGS parameter codes (pcodes); comparison thresholds; and reporting levels. Table_3_qw_indicators_v4.txt: Water-quality indicators in groundwater samples collected by the USGS NAWQA Project. Table_4_nutrients_v4.txt: Nutrients and dissolved organic carbon in groundwater samples collected by the USGS NAWQA Project. Table_5_major_ions_v4.txt: Major and minor ions in groundwater samples collected by the USGS NAWQA Project. Table_6_trace_elements_v4.txt: Trace elements in groundwater samples collected by the USGS NAWQA Project. Table_7_vocs_v4.txt: Volatile organic compounds (VOCs) in groundwater samples collected by the USGS NAWQA Project. Table_8_pesticides_v4.txt: Pesticides in groundwater samples collected by the USGS NAWQA Project. Table_9_radchem_v4.txt: Radionuclides in groundwater samples collected by the USGS NAWQA Project. Table_10_micro_v4.txt: Microbiological indicators in groundwater samples collected by

Groundwater-quality data were collected from 648 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program and are included in this report. Most of the wells (514) were sampled from January through December 2016 and 60 of them were sampled in 2013 and 74 in 2014. The data were collected from seven types of well networks: principal aquifer study networks, which are used to assess the quality of groundwater used for public water supply; land-use study networks, which are used to assess land-use effects on shallow groundwater quality; major aquifer study networks, which are used to assess the quality of groundwater used for domestic supply; enhanced trends networks, which are used to evaluate the time scales during which groundwater quality changes; vertical flow-path study networks, which are used to evaluate changes in groundwater quality from shallow to deeper depths; flow path study networks, which are used to evaluate changes in groundwater quality from shallow to deeper depths over a horizontal distance; and modeling support studies, which are used to provide data to support groundwater modeling. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including major ions, nutrients, trace elements, volatile organic compounds, pesticides, radionuclides, and some special interest constituents (arsenic speciation, chromium [VI] and perchlorate). These groundwater quality data are tabulated in a U.S. Geological Survey Data Series Report DS-1124 which is available at https://dx.doi.org/XXXXXX and in this data release. Some data from environmental samples collected in 2013-14 and quality-control samples collected in 2012-15 also are included in the associated data release. Data from samples collected in 2016 are associated with networks described in this report and have not been published previously; data from samples collected between 2012 and 2015 are associated with networks described in previous reports in this data series (Arnold and others, 2016a,b, 2017a,b, 2018a,b). There are 23 data tables included in this data release and they are referenced as tables 1-13 and appendix tables 4.10-4.19 in the larger work citation. There are 36 tables that are part of the larger work citation; the 13 tables not included in the data release are summary tables derived from some of the other tables (tables 1.1, 2.2-2.3, 3.1, 4.1-4.9). A version of table 1 is included in both the text and data release. This compressed file contains 23 files of groundwater-quality data in ASCII text tab-delimited format and one corresponding metadata in xml format that describes all the tables and attributes.

Groundwater-quality data were collected from 648 wells as part of the National Water-Quality Assessment Project of the U.S. Geological Survey National Water-Quality Program and are included in this report. Most of the wells (514) were sampled from January through December 2016 and 60 of them were sampled in 2013 and 74 in 2014. The data were collected from seven types of well networks: principal aquifer study networks, which are used to assess the quality of groundwater used for public water supply; land-use study networks, which are used to assess land-use effects on shallow groundwater quality; major aquifer study networks, which are used to assess the quality of groundwater used for domestic supply; enhanced trends networks, which are used to evaluate the time scales during which groundwater quality changes; vertical flow-path study networks, which are used to evaluate changes in groundwater quality from shallow to deeper depths; flow path study networks, which are used to evaluate changes in groundwater quality from shallow to deeper depths over a horizontal distance; and modeling support studies, which are used to provide data to support groundwater modeling. Groundwater samples were analyzed for a large number of water-quality indicators and constituents, including major ions, nutrients, trace elements, volatile organic compounds, pesticides, radionuclides, and some special interest constituents (arsenic speciation, chromium [VI] and perchlorate). These groundwater quality data are tabulated in a U.S. Geological Survey Data Series Report DS-1124 which is available at https://dx.doi.org/XXXXXX and in this data release. Some data from environmental samples collected in 2013-14 and quality-control samples collected in 2012-15 also are included in the associated data release. Data from samples collected in 2016 are associated with networks described in this report and have not been published previously; data from samples collected between 2012 and 2015 are associated with networks described in previous reports in this data series (Arnold and others, 2016a,b, 2017a,b, 2018a,b). There are 23 data tables included in this data release and they are referenced as tables 1-13 and appendix tables 4.10-4.19 in the larger work citation. There are 36 tables that are part of the larger work citation; the 13 tables not included in the data release are summary tables derived from some of the other tables (tables 1.1, 2.2-2.3, 3.1, 4.1-4.9). A version of table 1 is included in both the text and data release. This compressed file contains 23 files of groundwater-quality data in ASCII text tab-delimited format and one corresponding metadata in xml format that describes all the tables and attributes.

From October 2017 through September 2022, the National Water Quality Network (NWQN) monitored 110 surface-water river and stream sites and more than 1,800 groundwater wells for a large number of water-quality analytes, for which associated quality-control data and corresponding statistical summaries are included in this data release. The quality-control data—for samples that were collected in the field (at all 110 surface-water sites, 350 groundwater wells, and 16 quality-control-only sites), prepared in the laboratory, or prepared by a third party—can be used to assess the quality of environmental data collected by the NWQN through the estimation of bias and variability in reported results. The general analyte groups that were monitored at NWQN surface-water and (or) groundwater sites and have associated quality-control data in this data release include major ions, nutrients, trace elements, pesticides, volatile organic compounds, hormones, pharmaceuticals, radionuclides, microbial indicators, sediment, and environmental tracers. For each analyte group, the data tables contain results for one or more of the following types of quality-control samples, where relevant: blanks, matrix spikes, and replicates collected at field sites; laboratory blanks, reagent spikes, and matrix spikes prepared by the USGS National Water Quality Laboratory (NWQL) (quality-control samples prepared by other analyzing laboratories are not included in the current data release); and third-party blanks, spikes, and reference samples prepared by the USGS Quality Systems Branch (QSB). For each relevant analyte, tables of summary statistics characterize the frequency and concentrations of blank detections, the typical magnitude of and variability in spike and reference-sample recoveries, and the typical variability between replicate concentrations. Tables included in this data release: Table1_SiteList.txt: Information about National Water Quality Network sites that have associated quality-control data. Table2_AnalyteList.txt: Information about National Water Quality Network analytes that have associated quality-control data, including available aquatic-life and (or) human-health benchmarks and selected information regarding analytical methods. Table3_BlankData.txt: For all relevant analytes, results for blanks collected at field sites, prepared in the laboratory, or prepared by a third party. Table4_SpikeData.txt: For all relevant analytes, results for matrix spikes prepared in the field, matrix spikes prepared in the laboratory, reagent spikes prepared in the laboratory, or reagent spikes prepared by a third party. For matrix spikes, results of paired environmental samples are included. Table5_ReplicateData.txt: For all relevant analytes, results for field replicates and paired environmental samples. Table 6_ReferenceData.txt: For all relevant analytes, results for third-party reference samples. Table7_BlankStats.txt: For all relevant analytes, summary statistics for each type of available blank sample. Table8_SpikeStats.txt: For all relevant analytes, summary statistics for each type of available spike sample. Table9_ReplicateStats.txt: For all relevant analytes, summary statistics for field replicates. Table10_ReferenceStats.txt: For all relevant analytes, summary statistics for reference samples.