Geochemical data for aqueous, mine tailings, and sediment samples collected from the Big River and Meramec River drainage basins in southeastern Missouri are presented. The Big River drains historical lead, zinc, and barite mining districts, including the Old Lead Belt (OLB). Underground mining in the OLB resulted in large mine-waste chat piles and tailings impoundments that have released material laden with lead, zinc, and other trace elements to the Big River drainage basin. The Meramec River has also been affected by mining-related material transported by the Big River. Since the late 1980s, the U.S. Geological Survey (USGS) has been involved in investigations into the effects of mining on the Big River. The data presented here were generated as part of collaborations between the USGS Central Midwest Water Science Center, the USGS Mineral Resources Program, the U.S. Environmental Protection Agency, and the Missouri Department of Natural Resources. Flood deposit sediments were collected immediately after major flooding of the Big and Meramec Rivers in December 2016 and April 2017. Bed sediments and suspended sediments were collected by various methods during several field efforts from 2018 through 2022. Mine tailings were collected by coring on the former Federal mine tailings impoundment within St. Joe State Park in 2018. Concentrations of major and trace elements were determined for multiple particle size fractions of solid-phase samples, and multi-element analyses of deionized water leaches and sequential extractions were performed on select samples. Aqueous samples were collected from the Big River, tributaries, and mine and mine-waste seeps at near baseflow conditions during three different field efforts in 2018, 2019, and 2021. Aqueous samples were analyzed for anions and major and trace elements. Concentrations of major and trace elements in streambed and suspended sediments collected from the Big River drainage basin in 1988 and 1999 are also reported; these data were previously published in a USGS report but are provided here for convenient comparison.

This U.S. Geological Survey (USGS) data release contains data from stream water, groundwater, and soil samples collected in 2019 and 2020 in the North Quartz Creek watershed in central Colorado. Fourteen streambank wells were installed in pairs at seven locations in August 2020 to capture the emerging groundwater from the left bank and right banks (relative to downstream-facing direction) and a synoptic sampling campaign was conducted to quantify metal contributions to the stream. A continuous, instream injection of sodium bromide (NaBr) was initiated at the head of the 5 km study reach several days prior to the synoptic sampling campaign and maintained throughout the duration of the study. Bromide concentrations were subsequently used to determine streamflow in the primary study reach (upper 1.3 km) using the tracer-dilution method, and as an indicator of hydrologic connections between North Quartz Creek and subsurface water. Streamflow was quantified in a secondary study reach (lower 3.7 km) using data from a series of sodium chloride slug additions wherein specific conductivity readings were used as a surrogate for the tracer concentration. Surface water samples were collected along North Quartz Creek including inflows from the left (LBI) and right (RBI) banks. Soil and sediment samples were collected along the transport path from source material (natural weathering and mine tailings/mine drainage) to the stream.

This U.S. Geological Survey (USGS) data release contains data from stream water, groundwater, and soil samples collected in 2019 and 2020 in the North Quartz Creek watershed in central Colorado. Fourteen streambank wells were installed in pairs at seven locations in August 2020 to capture the emerging groundwater from the left bank and right banks (relative to downstream-facing direction) and a synoptic sampling campaign was conducted to quantify metal contributions to the stream. A continuous, instream injection of sodium bromide (NaBr) was initiated at the head of the 5 km study reach several days prior to the synoptic sampling campaign and maintained throughout the duration of the study. Bromide concentrations were subsequently used to determine streamflow in the primary study reach (upper 1.3 km) using the tracer-dilution method, and as an indicator of hydrologic connections between North Quartz Creek and subsurface water. Streamflow was quantified in a secondary study reach (lower 3.7 km) using data from a series of sodium chloride slug additions wherein specific conductivity readings were used as a surrogate for the tracer concentration. Surface water samples were collected along North Quartz Creek including inflows from the left (LBI) and right (RBI) banks. Soil and sediment samples were collected along the transport path from source material (natural weathering and mine tailings/mine drainage) to the stream.

This data release is part of a study designed to test geochemical methods that best delineate known mineral deposits in the northeast part of the Tanacross 1° x 3° quadrangle, within the Yukon-Tanana Upland region, Alaska. The total area sampled is about 3,200 km2. Extensive tundra cover and patchy spruce/alder vegetation and very limited outcrop exposure characterize the area. Soils and stream sediments contain mixtures of weathered bedrock, sand derived from dunes developed during the Pleistocene, and volcanic ash deposits from the 1.2 Ky eruption of the nearby Mount Churchill volcano. Several mineral deposits are known in the area, including the Late Cretaceous to earliest Tertiary porphyry Cu (+/-Mo-Au) deposits at Taurus, Bluff, and Oreo; and poorly understood epithermal(?) Cu-Au (+/- Pb-Zn) deposits at Pika, Fishhook, and Pushbush. Stream water and sediment samples were collected near these occurrences, as well as in surrounding areas, to determine methods that most effectively enhance geochemical signals related to mineralization. Sediment samples were collected during two sampling campaigns (2017 and 2018). Each sample was dried, homogenized, and split into multiple aliquots. One aliquot of sediment was subsequently sieved to recover the minus-80 mesh portion of the sample, whereas a second was sieved to recover the minus-230 mesh portion of the sample. Both aliquots were analyzed by three techniques, all of which included ICP-OES/ICP-MS analysis following (1) sodium peroxide fusion, 2) leaching by aqua regia; and 3) leaching by cold hydroxylamine-HCL. Stream water samples were collected from select sites in August 2018 and analyzed for cation and anion concentrations using high-resolution ICP-MS for cations and Ion Chromatography (IC) for anions.

This data release is part of a study designed to test geochemical methods that best delineate known mineral deposits in the northeast part of the Tanacross 1° x 3° quadrangle, within the Yukon-Tanana Upland region, Alaska. The total area sampled is about 3,200 km2. Extensive tundra cover and patchy spruce/alder vegetation and very limited outcrop exposure characterize the area. Soils and stream sediments contain mixtures of weathered bedrock, sand derived from dunes developed during the Pleistocene, and volcanic ash deposits from the 1.2 Ky eruption of the nearby Mount Churchill volcano. Several mineral deposits are known in the area, including the Late Cretaceous to earliest Tertiary porphyry Cu (+/-Mo-Au) deposits at Taurus, Bluff, and Oreo; and poorly understood epithermal(?) Cu-Au (+/- Pb-Zn) deposits at Pika, Fishhook, and Pushbush. Stream water and sediment samples were collected near these occurrences, as well as in surrounding areas, to determine methods that most effectively enhance geochemical signals related to mineralization. Sediment samples were collected during two sampling campaigns (2017 and 2018). Each sample was dried, homogenized, and split into multiple aliquots. One aliquot of sediment was subsequently sieved to recover the minus-80 mesh portion of the sample, whereas a second was sieved to recover the minus-230 mesh portion of the sample. Both aliquots were analyzed by three techniques, all of which included ICP-OES/ICP-MS analysis following (1) sodium peroxide fusion, 2) leaching by aqua regia; and 3) leaching by cold hydroxylamine-HCL. Stream water samples were collected from select sites in August 2018 and analyzed for cation and anion concentrations using high-resolution ICP-MS for cations and Ion Chromatography (IC) for anions.

This U.S. Geological Survey (USGS) data release contains data from stream water, groundwater, and stream sediment samples collected in August 2023 in the East Mancos River watershed in southwestern Colorado. Data were collected as part of a study aimed at identifying sources of elevated metal concentrations in the stream. Eighteen streambank wells were installed in pairs at nine locations to capture the emerging groundwater from the left and right banks (relative to downstream-facing direction) and a synoptic sampling campaign was conducted to quantify stream metal loads. A continuous, instream injection of sodium bromide (NaBr) was initiated at the head of the ~17 km study reach prior to the synoptic sampling campaign and maintained throughout the duration of the study. Bromide concentrations were subsequently used to determine streamflow in the upper ~2.7 km of the stream using the tracer-dilution method. Streamflow was quantified for tributaries and locations farther downstream using data from a series of sodium chloride slug additions wherein specific conductivity readings were used as a surrogate for the tracer concentration. Stream and groundwater samples, including the wells and inflows from the left (LBI) and right (RBI) banks, were collected mainly in the upper ~0.9 km of the stream course (primary study reach). Environmental tracer data were collected to better understand groundwater flowpaths to the stream. Stream sediment samples, including some ferricrete samples, were also collected to help identify potential instream and near-stream metal sources.

This U.S. Geological Survey (USGS) data release contains stream water chemistry and streamflow data collected in late August and early September, 2021 from 28 sites located throughout Colorado, USA. The sampled streams all drain high-elevation mountain watersheds in areas where the bedrock is hydrothermally altered and contains abundant sulfide minerals. Most sampled streams are therefore affected by natural acid-rock drainage. All sites had been sampled in prior years so that the 2021 data could be used to evaluate potential changes in stream water chemistry in recent decades. Streamflow was also quantified at most sites using data from a sodium chloride slug addition wherein specific conductivity readings were used as a surrogate for the tracer concentration.

This U.S. Geological Survey (USGS) data release contains stream water chemistry and streamflow data collected in late August and early September, 2021 from 28 sites located throughout Colorado, USA. The sampled streams all drain high-elevation mountain watersheds in areas where the bedrock is hydrothermally altered and contains abundant sulfide minerals. Most sampled streams are therefore affected by natural acid-rock drainage. All sites had been sampled in prior years so that the 2021 data could be used to evaluate potential changes in stream water chemistry in recent decades. Streamflow was also quantified at most sites using data from a sodium chloride slug addition wherein specific conductivity readings were used as a surrogate for the tracer concentration.

This U.S. Geological Survey (USGS) Data Release contains locations and concentrations of metals in various size fractions in floodplain-core, streambed-sediment samples, and sediment deposited on the flood plain from the December 2015 flood and underlying soils collected from along the Middle Big River and tributaries in the Southeast Missouri Barite District from 2012 to 2015. All samples were analyzed either by inductively-coupled plasma-mass spectrometry (ICP-MS) or x-ray fluorescence (XRF). Concentrations of metals in quality-assurance samples are also presented to evaluate the effect of sample splitting and compare the U.S. Environmental Protection Agency (EPA) and USGS Missouri Water Science Center XRF units. Major and trace elements included in this data release include aluminum, antinomy, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chromium, cobalt, copper, gallium, indium, iron, lanthanum, lead, lithium, magnesium, manganese, molybdenum, nickel, niobium, phosphorus, potassium, rubidium, scandium, silver, sodium, strontium, sulfur, tellurium, thallium, thorium, tin, titanium, tungsten, uranium, vanadium, yttrium, and zinc. These data tables are provided as machine readable access to the tables in the following publication: Smith, D.C., and Schumacher, J.G., 2018, Distribution of mining-related trace elements in streambed and flood-plain sediment along the middle Big River and tributaries in the Southeast Missouri Barite District, 2012–15: U.S. Geological Survey Scientific Investigations Report 2018–5103, 89 p., https://doi.org/10.3133/sir20185103.

This U.S. Geological Survey (USGS) Data Release contains locations and concentrations of metals in various size fractions in floodplain-core, streambed-sediment samples, and sediment deposited on the flood plain from the December 2015 flood and underlying soils collected from along the Middle Big River and tributaries in the Southeast Missouri Barite District from 2012 to 2015. All samples were analyzed either by inductively-coupled plasma-mass spectrometry (ICP-MS) or x-ray fluorescence (XRF). Concentrations of metals in quality-assurance samples are also presented to evaluate the effect of sample splitting and compare the U.S. Environmental Protection Agency (EPA) and USGS Missouri Water Science Center XRF units. Major and trace elements included in this data release include aluminum, antinomy, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chromium, cobalt, copper, gallium, indium, iron, lanthanum, lead, lithium, magnesium, manganese, molybdenum, nickel, niobium, phosphorus, potassium, rubidium, scandium, silver, sodium, strontium, sulfur, tellurium, thallium, thorium, tin, titanium, tungsten, uranium, vanadium, yttrium, and zinc. These data tables are provided as machine readable access to the tables in the following publication: Smith, D.C., and Schumacher, J.G., 2018, Distribution of mining-related trace elements in streambed and flood-plain sediment along the middle Big River and tributaries in the Southeast Missouri Barite District, 2012–15: U.S. Geological Survey Scientific Investigations Report 2018–5103, 89 p., https://doi.org/10.3133/sir20185103.