The Marcellus Shale Energy and Environment Laboratory (MSEEL) is a long-term field site and laboratory at the Northeast Natural Energy LLC (NNE) production facility, adjacent to the Monongahela River, located in western Monongalia County, West Virginia, USA. NNE began drilling two horizontal production wells, MIP (Morgantown Industrial Park) -5H and MIP-3H, in the Marcellus Shale in 2014. The wells were completed in December 2015. Large volumes of wastewater are generated with natural gas production. These wastewaters contain organic and inorganic chemical constituents from fracturing fluids used during drilling and stimulation of gas in host rocks/shale, as well as chemical compounds that are derived from formation water and the solid shale. Many of the organic and inorganic substances in the wastewater are potentially toxic and could pose an environmental risk if released due to spills, leaks, or unsafe disposal practices. An on-site storage tank and a separator tank (MIP-5H), both containing produced wastewater, were sampled from 2015 through 2019. The storage tank received wastewater from multiple wells (not just MIP-5H). The data associated with the chemical conditions of these two tanks, at the time of sampling, have been previously published in a companion data release (https://doi.org/10.5066/P9Q3Y16S). The current data release reports on a sub-set of produced water samples co-collected from the above-mentioned storage and separator tanks during the 2016-2019 period, which were reserved for explicit experiments and analyses associated with detailed geochemical characterization of both the solid phase and dissolved fractions. The eleven machine readable data files (*.csv format) provided herein, and the description of the data contained in each, are described in the Entity and Attribute section (xml tag 'eainfo') of this metadata file.

This data release provides multi-element data for drill core samples from the Mesoproterozoic Nonesuch Formation and Copper Harbor Conglomerate at the Copperwood copper deposit, Michigan, USA. Copper was determined by assay, and sulfur by inductively coupled plasma-optical emission spectrometry (ICP-OES) after aqua regia digestion for most samples. Multi-element whole rock analyses were determined for selected samples. The Copperwood copper deposit is a sediment-hosted stratiform copper deposit in the Presque Isle Syncline of the Upper Peninsula of Michigan. The deposit has a 2018 mineral resource estimate of 42.2 million metric tons (Mt) of measured plus indicated mineral resources in the Lower Copper Bearing Sequence at an average grade of 1.60 percent Cu and 3.84 grams per ton (g/t) Ag. The measured plus indicated mineral resource in the Upper Copper Bearing Sequence is estimated to be 7.1 Mt at an average grade of 1.21 percent Cu and 3.26 g/t Ag (Gignac, 2018). The mineral reserves for the Copperwood Project are estimated at 25.4 Mt at an average grade of 1.43 percent Cu and 3.83 g/t Ag (Gignac, 2018).

This data table includes the data source, identifiers for sampled wells, properties in the vicinity of San Juan Coal Mine where wells are located, sampling date, and results of groundwater chemistry analyses for arsenic, calcium, chloride, sodium, sulfate, sulfide and dissolved solids in milligrams per liter.

The Marcellus Shale Energy and Environment Laboratory (MSEEL) is part of the Northeast Natural Energy LLC (NNE) production facility on the Monongahela River in Monongalia County, West Virginia, USA. Natural gas extraction in the area creates large volumes of wastewater that may contain chemical compounds that pose risks to humans, animals, and the environment. The U. S. Geological Survey (USGS) has been studying the organic compounds in water produced from shale gas wells and in 2014, NNE started drilling two production wells in the Marcellus Shale. The well, MIP (Morgantown Industrial Park) -5H, was completed the following year. Samples were collected from this well. Large volumes of wastewater fluids were produced from this well and contain a mixture of chemicals added during hydraulic fracturing of the formation and chemical constituents from the host rocks. The original hydraulic fracturing fluids and the wastewater contain organic materials that could be toxic or pose risks to the environment if leaked, spilled, or improperly disposed of. This project was designed to collect comprehensive data from multiple sample types, including Monongahela River water, wastewater collected at the separator (during the flowback and produced-water phase), storage tank wastewater, and field blanks. Water samples for the analyses contained in this release were collected from July 2015 through December 2018. Samples of Monongahela River water were collected from a lined holding pond adjacent to the MIP well pad on November 5, 2015. Wastewater was intermittently sampled from the MIP-5H separator on the well pad from December 10, 2015, to December 6, 2018. The wastewater produced during the first two weeks of production was labeled as flowback water until December 23, 2015, then the wastewater produced after this date was defined as produced water. A storage tank at the well pad site was sampled on December 6, 2018. This data release contains non-target liquid chromatography/high-resolution mass spectrometry data.

The Marcellus Shale Energy and Environment Laboratory (MSEEL) is part of the Northeast Natural Energy LLC (NNE) production facility on the Monongahela River in Monongalia County, West Virginia, USA. Natural gas extraction in the area creates large volumes of wastewater that may contain chemical compounds that pose risks to humans, animals, and the environment. The U. S. Geological Survey (USGS) has been studying the organic compounds in water produced from shale gas wells and in 2014, NNE started drilling two production wells in the Marcellus Shale. The well, MIP (Morgantown Industrial Park) -5H, was completed the following year. Samples were collected from this well. Large volumes of wastewater fluids were produced from this well and contain a mixture of chemicals added during hydraulic fracturing of the formation and chemical constituents from the host rocks. The original hydraulic fracturing fluids and the wastewater contain organic materials that could be toxic or pose risks to the environment if leaked, spilled, or improperly disposed of. This project was designed to collect comprehensive data from multiple sample types, including Monongahela River water, wastewater collected at the separator (during the flowback and produced-water phase), storage tank wastewater, and field blanks. Water samples for the analyses contained in this release were collected from July 2015 through December 2018. Samples of Monongahela River water were collected from a lined holding pond adjacent to the MIP well pad on November 5, 2015. Wastewater was intermittently sampled from the MIP-5H separator on the well pad from December 10, 2015, to December 6, 2018. The wastewater produced during the first two weeks of production was labeled as flowback water until December 23, 2015, then the wastewater produced after this date was defined as produced water. A storage tank at the well pad site was sampled on December 6, 2018. This data release contains non-target liquid chromatography/high-resolution mass spectrometry data.

The Marcellus Shale Energy and Environmental Laboratory (MSEEL) field site in Morgantown, WV was established by West Virginia University in order to increase understanding of factors that affect resource recovery and environmental impacts from unconventional oil and gas development. The site, which is located in the Morgantown Industrial Park (MIP) adjacent to the Monongahela River, includes one well pad which hosts four horizontal gas wells that target the Marcellus Shale approximately 7400 ft below ground level. As part of the MSEEL study, the MIP 5H well was drilled in 2015. Water samples were collected from the holding pond used to hydraulically fracture the MIP 5H well (API 47-061-01699), and a time series of produced water samples were collected from the MIP 5H separator tank starting in 2016 when the well was opened for flowback and ending in 2019. This data release includes semi-quantitative analysis of polycyclic aromatic hydrocarbons (PAHs) identified in these water samples as well as a list of non-target compounds that were identified via gas chromatograph-mass spectrometry analysis and subsequent spectral matching against mass spectral libraries.