Great Salt Lake Composition and Rare Earth Speciation Analysis

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We have conducted aqueous speciation analyses of the Great Salt Lake (GSL) brine sample (Table 1) and a mock geo sample (Table 2) spiked with 1 ppb Tb and 100 ppb Tb. The GSL speciation (Figure 1) aligns with our basic speciation expectations that strong carbonate complexes would form at mid to higher pH's. Although we expected strong aqueous complexes with fluorides at neutral pH and with chlorides, and hydroxides at low pH, we observe that the dominant species in the low to mid pH range to be Tb3+ as a free ion. Still, we do see the presence of fluoride and chloride complexes within the expected low to mid pH range.

Technical Report-Rare Earth Element Data Associated with Oil and Gas Reservoir Rock

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This work was developed to complement the geochemical assessments of produced water and geothermal water samples. Specifically, this task was designed to test the influence of reservoir rock-type and corresponding mineralogy/geochemistry on the concentrations of REE found in oil and gas produced waters. There has been no direct investigation of REE reactions relative to rock-type in deep oil and gas brine prior to this investigation.

Rare Earth Element Biomining from the Great Salt Lake Brine Using Engineered E. Coli

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This data describes rare earth element adsorption onto E. coli cells engineered to express a lanthanide binding tag (LBT). We used a Great Salt Lake synthetic solution as the background matrix with Tb added to 1-10,000 ppb, concentrations much lower than the competing ions present. Our results showed that Tb binds to LBT, even in the presence of high concentrations of competing metals. We also tested REE adsorption at elevated temperatures (up to 100 degrees Celsius), and observed that Tb adsorption increases with temperature of to 70 degrees Celsius, and then remains constant until 100 degrees Celsius. Data analyses were performed using an ICP-MS at UCSC.

Raft River Geothermal Field Well Head Brine Sample

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Raw data and data workup of assay for real-world brine sample. Brine sample was taken at the well head.

Raft River Geothermal Field Well Head Brine Sample

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Raw data and data workup of assay for real-world brine sample. Brine sample was taken at the well head.

Aqueous Rare Earth Element Patterns and Concentration in Thermal Brines Associated with Oill and Gas Production

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This study is part of a joint effort by the University of Wyoming (UW) School of Energy Resources (SER), the UW Engineering Department, Idaho National Laboratories (INL), and the United States Geological Survey (USGS) to describe rare earth element concentrations in oil and gas produced waters and in coal-fired power station ash ponds. In this work we present rare earth element (REE) and trace metal behavior in produced water from four Wyoming oil and gas fields and surface ash pond water from two coal-fired power stations. Using the methods of the INL team members, we measured REEs in high salinity oil and gas produced waters. Our results show that REEs exist as a dissolved species in all waters measured for this project, typically within the parts per trillion range.

Aqueous Rare Earth Element Patterns and Concentration in Thermal Brines Associated with Oill and Gas Production

공공데이터포털

This study is part of a joint effort by the University of Wyoming (UW) School of Energy Resources (SER), the UW Engineering Department, Idaho National Laboratories (INL), and the United States Geological Survey (USGS) to describe rare earth element concentrations in oil and gas produced waters and in coal-fired power station ash ponds. In this work we present rare earth element (REE) and trace metal behavior in produced water from four Wyoming oil and gas fields and surface ash pond water from two coal-fired power stations. Using the methods of the INL team members, we measured REEs in high salinity oil and gas produced waters. Our results show that REEs exist as a dissolved species in all waters measured for this project, typically within the parts per trillion range.

Brine Geochemistry from Soda Geyser, Idaho

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These brine samples are collected from the Soda Geyser (a thermal feature, temperature ~30 C) in Soda Springs, Idaho. These samples also represent the overthrust brines typical of oil and gas plays in western Wyoming. Samples were collected from the source and along the flow channel at different distances from the source. By collecting and analyzing these samples we are able to increase the density and quality of data from the western Wyoming oil and gas plays. Furthermore, the sampling approach also helped determine the systematic variation in REE concentration with the sampling distance from the source. Several geochemical processes are at work along the flow channels, such as degassing, precipitation, sorption, etc.

Assessing REE Concentrations in Geothermal and Oil and Gas Produced Waters: A Potential Domestic Source of Strategic Mineral Commodities

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The project team collected and analyzed 224 water samples and 101 matching rock samples. INL's improved method of measuring aqueous REEs allows study of samples previously thought too volume limited to measure. The study found that aqueous REEs occur at trace levels in all analyzed samples, and sometimes exceed ocean REE concentrations by a factor of 1,000. No significant predictive relationship to lithology, reservoir temperature, nor salinity was discovered, but aqueous REE concentration appears spatially controlled. Future work is needed to find the spatially-dependent variable that controls aqueous REE concentration.

Aqueous Rare Earth Elements, Concentration, and Stable Isotopes in Deep Basin Brines, Wyoming

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Presentation given to National Groundwater Association meeting on deep basin brines. This presentation discusses why produced waters are being observed, the importance of REE's, the study areas examined, the data collected, and the relationship between REE concentration and possible ligands.