The NARSTO_EPA_SS_ST_LOUIS_AIR_CHEM_PM_MET_DATA were obtained between April 11, 2001 and July 21, 2003 during the St. Louis - Midwest Supersite program.The overall goal of the St. Louis - Midwest Supersite was to conduct aerosol physical and chemical measurements needed by the health effects community, the atmospheric science community and the regulatory community to properly assess the impact of particulate matter exposure on human health and to develop control strategies to mitigate these effects. Metropolitan St. Louis is a major population center well isolated from other urban centers of even moderate size, and is impacted by both distant and local sources. Local industry includes manufacturing,refining, and chemical plants. St. Louis is climatologically representative of the country's eastern interior, affected by a wide range of synoptic weather patterns and free of localized influences from the Great Lakes, Ocean, Gulf, and mountains. It accordingly provides an ideal environment for studying the sources, transport, and properties of ambient particles.The initial data types included:1) 5-minute PM 2.5 black carbon (880 nm) and uv-absorbing carbon (370 nm) measured by a Magee Scientific Aethalometer (Model AE-21).2) 1-hour PM 2.5 elemental carbon and blank-corrected organic carbon from semicontinuous thermo-optical analysis by the ACE-ASIA method.3) 24-hour PM 2.5 elemental carbon and organic carbon (both blank-corrected) from integrated filter with offline thermo-optical analysis by the ACE-ASIA method.4) 30-minute PM 2.5 metal composition from samples collected with a Semicontinuous Elements in Aerosol Sampler (SEAS) II.5) 5-minute meteorological data (wind, temperature, RH, solar radiation, atmospheric pressure, and precipitation) measured with a Climatronics anemometer, wind vane, thermocouple, lithium chloride sensor, pyranometer, barometer, and tipping bucket.6) 24-hour PM 1.0 filter mass concentration measured by sharp cut cyclone and gravimetric analysis.7) 1-hour PM 2.5 mass measured by an Andersen Continuous Ambient Mass Monitoring System (CAMMS).8) 24-hour PM 2.5 and PM 10 filter mass by Harvard Impactors and laboratory gravimetric analysis.The U.S. EPA Particulate Matter (PM) Supersites Program was an ambient air monitoring research program designed to provide information of value to the atmospheric sciences, and human health and exposure research communities. Eight geographically diverse projects were chosen to specifically address these EPA research priorities: (1) to characterize PM, its constituents, precursors, co-pollutants, atmospheric transport, and its source categories that affect the PM in any region; (2) to address the research questions and scientific uncertainties about PM source-receptor and exposure-health effects relationships; and (3) to compare and evaluate different methods of characterizing PM including testing new and emerging measurement methods. NARSTO (formerly North American Research Strategy for Tropospheric Ozone) is a public/private partnership, whose membership spans government, the utilities, industry, and academe throughout Mexico, the United States, and Canada. The primary mission is to coordinate and enhance policy-relevant scientific research and assessment of tropospheric pollution behavior; activities provide input for science-based decision-making and determination of workable, efficient, and effective strategies for local and regional air-pollution management. Data products from local, regional, and international monitoring and research programs are available.

The NARSTO_EPA_SS_HOUSTON_TEXAQS2000_PM_FTIR measurement data consist of absolute absorbance areas for organonitrates, sulfate, aliphatic carbon and carbonyl compounds for size segregated particulate matter collected using a Herring Low Pressure Impactor (LPI). These data were collected during August and September 2000 at the Houston PM Supersite locations (LaPorte, HRM3, and Aldine) during the Texas Air Quality Study 2000 (TexAQS).The Houston Supersite is one of several Supersites that was established in urban areas within the United States by the U.S. Environmental Protection Agency (EPA) to better understand the measurement, sources, and health effects of suspended particulate matter (PM). The overall goals were to characterize the composition and identify the sources of particulate matter in Southeastern Texas, to develop and test new methods for characterizing fine particulate matter, and to collect data on the physical and chemical characterization of fine particulate matter that can be used to support exposure and health effects studies.NARSTO (formerly North American Research Strategy for Tropospheric Ozone) is a public/private partnership, whose membership spans government, the utilities, industry, and academe throughout Mexico, the United States, and Canada. The primary mission is to coordinate and enhance policy-relevant scientific research and assessment of tropospheric pollution behavior; activities provide input for science-based decision-making and determination of workable, efficient, and effective strategies for local and regional air-pollution management. Data products from local, regional, and international monitoring and research programs are available.

The NARSTO_SOS_SC_UPSTATE_PM25_COMPOSITION data were collected during July 2001 and January of 2002 to elucidate the seasonal variability of the aerosols. Samples were collected at a rural location in South Carolina, beginning and ending at midnight in order to associate each sampling event with a calendar day. In all, 40 samples per month were collected (including blanks).The purpose of the study was to determine experimentally the concentration and chemical composition of fine particulate matter (PM2.5, particles with a diameter less than 2.5 um) in South Carolina. The collection of PM2.5 samples on Teflon filters was carried out using a cyclone-based system. Ion chromatography analysis for anions and cations was performed, as well as x-ray fluorescence (XRF) analysis for crustal metals. PM2.5 samples on quartz filters were also collected in order to determine the organic and elemental carbon (EC/OC) particle concentration.The average concentration for PM2.5 during July of 2001 was 20.85 mg/m3. The major components of the aerosol were organic compounds (38.5%) and sulfates (34.7%). During January of 2002, the average concentration for PM2.5 was 9.4 mg/m3. Again, the major components of the aerosol were organic compounds (64.1%) and sulfates (21.9%).NARSTO (formerly North American Research Strategy for Tropospheric Ozone) is a public/private partnership, whose membership spans government, the utilities, industry, and academe throughout Mexico, the United States, and Canada. The primary mission is to coordinate and enhance policy-relevant scientific research and assessment of tropospheric pollution behavior; activities provide input for science-based decision-making and determination of workable, efficient, and effective strategies for local and regional air-pollution management. Data products from local, regional, and international monitoring and research programs are available.

NARSTO_Texas_PM2.5_Sampling_and_Analysis_Study_1997-1998_ is the North American Research Strategy for Tropospheric Ozone (NARSTO) Texas Particulate Matter (PM) 2.5 Sampling and Analysis Study: 1997-1998 Data. The data for this product was collected from March 11, 1997 to March 12, 1998. The City of Houston, the Texas Natural Resource Conservation Commission (TNRCC), and the Houston Regional Monitoring Network sponsored sampling and analysis of PM2.5 samples taken over the course of one year, from March 11, 1997 to March 12, 1998. Objectives of the study were to determine the levels and chemical composition of PM2.5 in Houston and other cities in Texas and to determine the background levels and chemical composition of PM2.5 transported into Houston. During the sampling effort, 24-hour PM2.5 mass measurements were acquired from 15 sites throughout the state of Texas, using DRI's MEDVOL particle samples. All of the Teflon filters were analyzed for mass by gravimetry and a selected subset of the Teflon and quartz fiber filters were subjected to full chemical analysis. These measurements were taken in anticipation of the U.S. EPA revising PM2.5 and PM10 NAAQS. These results could be used to establish background PM conditions and determine compliance with new PM standards. Various sampler configurations allow evaluation of data precision, accuracy, and validity. NARSTO, which has since disbanded, was a public/private partnership, whose membership spanned across government, utilities, industry, and academe throughout Mexico, the United States, and Canada. The primary mission was to coordinate and enhance policy-relevant scientific research and assessment of tropospheric pollution behavior; activities provide input for science-based decision-making and determination of workable, efficient, and effective strategies for local and regional air-pollution management. Data products from local, regional, and international monitoring and research programs are still available.

NARSTO_PAC2001_LANGLEY_GAS_PM_MET_DATA was obtained between August 8 and September 2, 2001 during the Pacific 2001 Air Quality Study (PAC2001).The Langley Ecole Lochiel (LEL) site was at 49.0289 N and -122.6025 W and at 90m above sea level (a.s.l). The site was surrounded by hobby farms and by relatively few country roads that are lined with both coniferous and deciduous trees, with little change in terrain heights within a radius of 15 km. Nontraditional agricultural practices, such as mushroom and chicken farming and small orchards, are common within this radius of the site. The nearest small urban center, Langley, is about 6 km north of the site. The site was approximately 10 km to the major expressways of Highway 1 in Canada and I-5 in the US and was approximately 6km to Highway 1A in Canada. Particle sampling was done in the center of an unobstructed field of approximately 30-50m2 about 2.5m from ground. On-site measurements were conducted from five temporary labs with inlets about 5m above ground. Measurements at this site, from August 13th to 31st, were intended to address the unknowns related to particles and ozone, with an emphasis on the transition from the urban mix to a suburban/rural setting, particularly the impact of agricultural sources on the particulate matter formation and evolution. Similar to the instrumentation package at Slocan Park site, the instrumentation package includes measurements in five categories.1) Measurements related to the precursors of fine PM and the oxidation environment in which the fine PM is formed. 2) Measurements related to the characterization of fine PM and the evolution process of PM.3) Measurements related to the emission of fine PM and its precursors in the valley.4) Measurements related to the mapping of fine PM horizontal and vertical distribution in the valley.5) Measurements of meteorological parameters in the valley. Measurements included detailed gas phase measurements of NOx=NOy (total and speciated), CO, O3, SO2, VOCs, OVOCs, carbonyls, NH3, HOx, and NH3 intended for a detailed understanding of the oxidation environment and chemical processes in which both O3 and secondary particulate matter are formed. Detailed measurements were made on size distributed inorganic ionic components, organic carbon, elemental carbon, and mass from 0.05 to 18 mm AD twice a day. High-time resolution measurements using a second AMS were made, measuring the size distribution of inorganic species and homologues of organic species from 0.06 to 0.7 mm. Detailed organic carbon speciation measurements, carbon isotope characterization, sulfur isotope characterization, and amorphous carbon were made for particles 2.5 mm on 10-h day samples collected twice daily. The gas-particle partitioning of semi-volatile organic compounds was studied using a Hi-cap denuder sampling system and detailed lab organic analyses. Continuous mass measurements for particles 2.5 mm were made using a tapered element oscillating microbalance (TEOM)with a diffusion dryer on the inlet. Particle number size distributions were measured from 0.01 to 3 mm using a DMA and an optical probe. Hygroscopic properties of particles were measured at two particle sizes using two DMAs in tandem. For NH3, HNO2, HNO3, HCHO, and PM 2.5 mm mass measurements and the particle chemical size distributions, more than one technique were deployed at this site. The multiple measurements of these species provided a test of the performance and validation of the different techniques and ensure that instrument biases were corrected. They also provide complementing data of different characteristics, such as better sensitivities versus time resolution. The diurnal evolution of the boundary layer height was studied using a scanning LIDAR that scanned the north, east and west quadrants. Radiation measurements, both UV and visible, were done using an Eppley and a CIMEL sun photometer. Vertical distribution of certain parameters, such as O3 and meteorological

The NARSTO_EPA_SS_HOUSTON_NO3_SO4_C_DATA files contain continuous measurements of PM2.5 nitrate, PM2.5 sulfate, and PM2.5 carbon collected during August 12, 2000 through November 5, 2001 at the Aldine, Deer Park, and LaPorte Houston Supersite monitoring locations. Nitrate measurements were collected using the R&P 8400N Method. Sulfate and carbon measurements were collected using the Prototype ADI Particulate Sulfate and Carbon Monitor Method.The Houston Supersite is one of several Supersites that was established in urban areas within the United States by the U.S. Environmental Protection Agency (EPA) to better understand the measurement, sources, and health effects of suspended particulate matter (PM). The overall goals were to characterize the composition and identify the sources of particulate matter in Southeastern Texas, to develop and test new methods for characterizing fine particulate matter, and to collect data on the physical and chemical characterization of fine particulate matter that can be used to support exposure and health effects studies.NARSTO (formerly North American Research Strategy for Tropospheric Ozone) is a public/private partnership, whose membership spans government, the utilities, industry, and academe throughout Mexico, the United States, and Canada. The primary mission is to coordinate and enhance policy-relevant scientific research and assessment of tropospheric pollution behavior; activities provide input for science-based decision-making and determination of workable, efficient, and effective strategies for local and regional air-pollution management. Data products from local, regional, and international monitoring and research programs are available.

NARSTO_STIFS_CANADA_PM_INORG_VOC_DATA is the North American Research Strategy for Tropospheric Ozone (NARSTO) Supersite Transboundary Intensive Field Study (STIFS) Particulate Matter (PM) Inorganic Volatile Organic Compounds DataData was collected in the Summer-Winter-Summer of 2001-2002 during the The goal of STIFS was the measurement of PM2.5 composition and related pollutants to improve estimates of the local vs long-range transport contribution to particles. The regions of interest were from SW Ontario to SW Quebec, and the Saturna/Vancouver area. In addition to the long-range transport emphasis, the improved time resolution in the data sets provide more detail for a variety of purposes, especially process studies and model development. STIFS particle-related measurements included: daily ambient meteorological measurements; real-time single particle size and chemistry; high time resolution OC, BC and particle nitrate; high time resolution particle sulfate; size-distribution of organic and element carbon; organic speciation; mass and water soluble organics and inorganics; particle mass and trace metals; and particle mass and inorganic ions. A companion document describing the project in greater detail and showing monitoring locations is available. Data archived at this time are the mass and water soluble organics and inorganics, speciated volatile organic carbon gas phase measurements, PM2.5 and PM2.5-10 mass concentration, and elemental and organic carbon mass concentrations. It is known that U.S. sources contribute significantly to the regional particle levels during certain time periods and likely have a significant impact on the annual average. However, sources within Ontario, Quebec and B.C. also play a role and better information on the relative importance of these sources vs U.S. sources is critical to policy development. Improved information on this issue can be obtained through more detailed ambient measurements in urban and rural areas and through the use of models. The study provided the measurements needed to infer more about the sources of particles in areas impacted by regional transport and to improve regional models (e.g., AURAMS and Models-3/CMAQ) for future application. NARSTO, which has since disbanded, was a public/private partnership, whose membership spanned across government, utilities, industry, and academe throughout Mexico, the United States, and Canada. The primary mission was to coordinate and enhance policy-relevant scientific research and assessment of tropospheric pollution behavior; activities provide input for science-based decision-making and determination of workable, efficient, and effective strategies for local and regional air-pollution management. Data products from local, regional, and international monitoring and research programs are still available.

NARSTO_EPA_SS_PITTSBURGH_PM_COMPOSITION_DATA is the North American Research Strategy for Tropospheric Ozone (NARSTO) Environmental Protection Agency (EPA) Supersite (SS) Pittsburgh Particulate Matter (PM) Composition Data. It was obtained between June 30 and September 1, 2001 during the Pittsburgh Air Quality Study (PAQS). The data set provides PM Composition Data of the following types:1) PM2.5 nitrate and PM2.5 sulfate.2) Semi-Continuous Organic and Elemental Carbon Measurements.3) Air concentrations of water soluble PM2.5 aerosol species and water soluble gases, as measured with the CMU steam sampler - IC combination.4) Manual filter-based PM2.5 element measurements from microwave decomposition of filters followed by Inductively Coupled Plasma Mass Spectrometer analysis.5) Manual filter-based PM10 element measurements from microwave decomposition of filters and Inductively Coupled Plasma Mass Spectrometer analysis.6) Manual filter-based PM2.5 inorganic composition with analysis performed using ion chromatography.7) Manual filter-based PM2.5 organic and elemental carbon measurements with analysis performed using a Thermal Optical Transmission carbon analyzer.8) Measurements of PM composition size distributions using a MOUDI cascade impactor.9) PM2.5 organic and elemental carbon concentrations from an activated carbon denuder/quartz filter/charcoal impregnated fiber filter backup combination. Quartz filters analyzed using a Thermal/Optical transmittance carbon analyzer.10) Fog chemistry dataPAQS, along with the Pittsburgh Supersite Program, was a comprehensive, multi-disciplinary investigation to characterize the ambient PM in the Pittsburgh region, to improve understanding the links between ambient PM and public health, and to develop new instrumentation for PM measurements. The Pittsburgh Supersite was designed to achieve several objectives: to determine the physical and chemical characteristics of PM in the Pittsburgh region; to develop and evaluate the next generation of atmospheric aerosol monitoring techniques; to update emission profiles for important regional sources; to quantify the impact of the various sources on the local PM concentrations; and to predict changes in the PM characteristics due to proposed changes in emissions. The last objective was based on concurrent modeling studies and was designed to support the development of regulations. These objectives were addressed through four components of the research: (1) ambient monitoring at a central site and a set of satellite sites in the region; (2) an instrument development and evaluation study; (3) a data analysis and synthesis component; and (4) a comprehensive modeling component.The central supersite was located on a grassy hill in a large urban park adjacent to the Carnegie Mellon University campus, approximately 6km east of downtown Pittsburgh. It was separated from the city in the predominant upwind direction (south and west) by roughly 1km of parkland. It was at least several hundred meters from any other major source of air pollution: the site was positioned approximately 50m past the end of a dead end street, and several hundred meters from the nearest heavily traveled street. Five additional sites were operated as Satellite sites to character the spatial variation of the PM. The measurement campaign lasted for 14 months (July 2001-September 2002). Intensive monitoring was performed during two periods, from 1 July to 3 August 2001 (ESP01) and 1 January to 15 January, 2002 (ESP02). Baseline monitoring was conducted for the rest of the study. Baseline measurements included daily filter samples for fine particle mass and composition (OC/EC, major ions, elemental composition). The U.S. EPA PM Supersites Program was an ambient air monitoring research program designed to provide information of value to the atmospheric sciences, and human health and exposure research communities. Eight geographically diverse projects were chosen to specifically address these