During the ice stations, sea ice, brine/slush, snow and under-ice water sampling were collected for CO2 concentration measurement as dissolved inorganic carbon (DIC). Ice cores were collected using a Kovacs 9 cm diameter ice corer. The ice core for DIC was cut directly after retrieval with a stainless steel folded saw. The core was cut generally into 10 cm sections (20 cm when ice cores were higher than 200 cm) and put into zip-lock polyethylene bags. Care was taken to use laboratory gloves when collecting the cores. For brine sampling, partial core holes were drilled into the ice (so called sackholes), usually to a depth of 25 cm and 50 cm. At site with flooding, brine collection was not possible, and samples of the surface slush were collected instead. Slush was collected by plastic shovel. Snow samples were also collected. Under-ice water was collected with a Teflon water sampler (GL Science Inc., Japan) 1, 3, 5 m below the bottom of the sea ice. In addition, CTD water sampling was examined at each station. The cores were taken back to the ship, and transferred to the gas tight bag (GL Science Inc., Japan), and then ice was melted at about +4 degrees C in a refrigerator. Melted samples were sub-sampled for each component. The snow samples were treated in the same manner as the sea ice samples for further analysis. The dissolved inorganic carbon (DIC) of seawater was determined by coulometry [Johnson et al. 1985] using a coulometer (CM5012, UIC Inc., Binghamton, NY, USA). DIC measurement was calibrated with reference seawater materials (Batch AG; KANSO Technos Co., Ltd., Osaka, Japan) traceable to the Certified Reference Material distributed by Prof. A. G. Dickson (Scripps Institution of Oceanography, La Jolla, CA, USA). The standard deviation for DIC calculated from 20 subsamples taken from a reference seawater material (DIC = 2084.5 micro mol L-1) was 1.4 micro mol L-1. Data available: excel files containing sampling station name, dates, and DIC concentration.

Gas Flux over Sea Ice We observed amount of gas exchange between sea ice and atmosphere. At the ice station, semi-automated chambers developed in Japan, were used for measurement of air-sea ice CO2 flux. These chambers could be used to examine spatial variability and also temporal variability of gas flux over sea ice. Samples were also taken from the snow and ice in order to measure CH4 and VOC, however these analyses will be conducted post-voyage. This metadata record will be updated in future to reflect the analysis. The chambers are designed to be placed over a snow and sea ice. When the lid is closed, CO2 concentration was measured. The opening and closing functions of the chambers are automated and were set to a 30 minutes interval. CO2 concentration (as voltage) were recorded in the data logger (CR10X, Campbell Scientific Inc.) and downloaded after the experiments. Raw data are contained in the excel files. During the CO2 flux measurement, we collected the snow, sea ice, brine/slush and under-ice water. Snow and sea ice samples were melted after sampling in PVDF film bags (like Tedlar bags in order to avoid gas exchange with ambient air) in 4C temperature and treated for analysis. A chemical analysis for carbonate systems and VOC (water), salinity, nutrient, pigment and oxygen isotopic ratio samples will take place in Japan after the voyage for analysis. During the cruise, to examine ice growth processes, we made sea ice thin-section to classify the ice cores into granular ice, columnar ice or mixed granular and columnar ice (Eicken and Lange, 1989). The CO2 data are contained in Excel spreadsheets. These use Japanese column headings. Calcium Carbonate (CACO3.6H20) as Ikaite in Sea Ice and Snow At each listed ice station we collected sea-ice cores using a Kovacs 9cm ice corer. Cores were sectioned into 10-20cm and melted at 4 degrees C, filtered and dried for later analysis of Calcium Carbonate in a home laboratory using an ICP, which produces text file outputs (included). Also included is a spreadsheet listing the cores, and the calcium carbonate measurements.

This metadata record is a 'Parent' metadata record for ASAC project 2720. See the link for the related 'Child' metadata records. The overall objective is to characterise Southern Ocean marine ecosystems, their influence on carbon dioxide exchange with the atmosphere and the deep ocean, and their sensitivity to past and future global change including climate warming, ocean stratification, and ocean acidification from anthropogenic CO2 emissions. In particular we plan to take advantage of naturally-occurring, persistent, zonal variations in Southern Ocean primary production and biomass in the Australian Sector to investigate the effects of iron addition from natural sources, and CO2 addition from anthropogenic sources, on Southern Ocean plankton communities of differing initial structure and composition. SAZ-SENSE is a study of the sensitivity of Sub-Antarctic Zone waters to global change. A 32-day oceanographic voyage onboard Australia's ice-breaker Aurora Australis was undertaken in mid-summer (Jan 17 - Feb. 20) 2007 to examine microbial ecosystem structure and biogeochemical processes in SAZ waters west and east of Tasmania, and also in the Polar Frontal Zone south of the SAZ. The voyage brought together research teams from Australasia, Europe, and North America, and was led by the ACE CRC, CSIRO Marine and Atmospheric Research, and the Australian Antarctic Division. The overall goal is to understand the controls on Sub-Antarctic Zone productivity and carbon cycling, and to assess their sensitivity to climate change. The strategy is to compare low productivity waters west of Tasmania (areas with little phytoplankton) with higher productivity waters to the east, with a focus on the role of iron as a limiting micro-nutrient. The study also seeks to examine the effect of rising CO2 levels on phytoplankton - both via regional intercomparisons and incubation experiments. Available for download from this metadata record are various datasets collected from the voyage: An image showing a map of the cruise track. An excel document detailing hourly position checks of the ship. An excel document detailing the event log for the voyage. A word document detailing prospective papers produced from the voyage. Finally a link is available for users to access the special volume of publications produced as a result of this voyage.

This dataset provides in situ airborne measurements of atmospheric carbon monoxide (CO), carbon dioxide (CO2), methane (CH4), and water vapor concentrations, plus air temperature, pressure, relative humidity, and wind speed values over Alaska and the Yukon and Northwest Territories of Canada during the Arctic Carbon Aircraft Profile (Arctic-CAP) monthly sampling campaigns from April-November 2017. Observations have been averaged to a 10-second interval and are reported with the number of samples (N) and standard deviation. During each of the six monthly campaigns, flights over the Arctic-Boreal Vulnerability Experiment (ABoVE) domain included 25 vertical profiles, from the surface up to 6 km altitude, at locations selected to complement regular long-term vertical profiles, remote sensing data, and ground-based flux tower measurements.

Carbonate chemistry data sets for the Antarctic Free Ocean Carbon Dioxide Enrichment experiment, Casey Station, East Antarctica, 2014/15. Project Summary: Currently, a quarter of the CO2 we emit is absorbed by the ocean. CO2 absorption in seawater changes its chemistry – reducing ocean pH (raising its acidity) – which has significant impacts on biological processes and serious implications for the resilience of marine ecosystems. As CO2 is more soluble in cold water we expect polar ecosystems to bear the heaviest burden of this 'ocean acidification'. We will perform the first in situ polar CO2 enrichment experiment to determine the likely impacts of ocean acidification on Southern Ocean sea-floor communities under increasing CO2 emissions.

Continuous underway measurements of sea surface (7 metres depth)and atmospheric carbon dioxide. Data format .txt extension comma delimited files. 1 file per 24 hours. Naming similar to AA03607_001-0000 (voyage_julian day_HH:MM). Excel readable format. 58 columns of data. Measurements were made on the CEAMARC voyage of the Aurora Australis - voyage 3 of the 2008-2008 summer season.

This data set was collected from a ocean acidification minicosm experiment performed at Davis Station, Antarctica during the 2014/15 summer season. It includes: - description of methods for all data collection and analyses. - environmental data logged throughout the experiment; nutrients, temperature, light climate. - carbonate chemistry data; pH (on Total scale), fugacity of CO2, dissolved inorganic carbon concentration, practical alkalinity, Omega calculations for both araganite and calcite. - product datasheet (including transmission spectra) of Osram 150W HQI-TS/NDL metal halide lamps.

TL2CO2N_8 is the Tropospheric Emission Spectrometer (TES)/Aura Level 2 Carbon Dioxide Nadir Version 8 data product. TES was an instrument aboard NASA's Aura satellite and was launched from California on July 15, 2004. Data collection for TES is complete. TES Level 2 data contain retrieved species (or temperature) profiles at the observation targets and the estimated errors. The geolocation, quality, and other data (e.g., surface characteristics for nadir observations) were also provided. L2 modeled spectra were evaluated using radiative transfer modeling algorithms. The process, referred to as retrieval, compared observed spectra to the modeled spectra and iteratively updated the atmospheric parameters. L2 standard product files included information for one molecular species (or temperature) for an entire global survey or special observation run. A global survey consisted of a maximum of 16 consecutive orbits.Nadir observations, which point directly to the surface of the Earth, are different from limb observations, which are pointed at various off-nadir angles into the atmosphere. Nadir and limb observations were added to separate L2 files, and a single ancillary file was composed of data that are common to both nadir and limb files. A Nadir sequence within the TES Global Survey was a fixed number of observations within an orbit for a Global Survey. Prior to April 24, 2005, it consisted of two low resolution scans over the same ground locations. After April 24, 2005, Global Survey data consisted of three low resolution scans. The Nadir standard product consists of four files, where each file is composed of the Global Survey Nadir observations from one of four focal planes for a single orbit, i.e. 72 orbit sequences. The Global Survey Nadir observations only used a single set of filter mix. A Global Survey consisted of observations along 16 consecutive orbits at the start of a two day cycle, over which 4,608 retrievals were performed. Each observation was the input for retrievals of species Volume Mixing Ratios (VMRs), temperature profiles, surface temperature, and other data parameters with associated pressure levels, precision, total error, vertical resolution, total column density, and other diagnostic quantities. Each TES Level 2 standard product reported information in a swath format conforming to the HDF-EOS Aura File Format Guidelines. Each Swath object was bounded by the number of observations in a global survey and a predefined set of pressure levels, representing slices through the atmosphere. Each standard product could have had a variable number of observations depending upon the Global Survey configuration and whether averaging was employed. Also, missing or bad retrievals were not reported. Further, observations were occasionally scheduled on non-global survey days. In general they were measurements made for validation purposes or with highly focused science objectives. Those non-global survey measurements were referred to as “special observations.”A Limb sequence within the TES Global Survey was three high-resolution scans over the same limb locations. The Limb standard product consists of four files, where each file is composed of the Global Survey Limb observations from one of four focal planes for a single orbit, i.e. 72 orbit sequences. The Global Survey Limb observations used a repeating sequence of filter wheel positions. Special Observations could only be scheduled during the 9 or 10 orbit gaps in the Global Surveys, and were conducted in any of three basic modes: stare, transect, step-and-stare. The mode used depended on the science requirement. Each limb observation Limb 1, Limb 2 and Limb 3, were processed independently. Thus, each limb standard product consisted of three sets where each set consisted of 1,152 observations. For TES, the swath object represented one of these sets. Thus, each limb standard product consisted of three swath objects, one for each observation, Limb 1, Limb 2, and Limb 3. The