Gold mineralization at the Mt. Skukum deposit occurs in nearly vertical quartz-carbonate veins which crosscut flat-lying andesites with a NNE trend. The mineralized veins represent the second stage of a two stage hydrothermal system, the first of which resulted in emplacement of thin chalcedonic veinlets. These two stages of veins are probably indicative of an evolving hydrothermal fluid rather than being representative of two separate events. Vein emplacement is one of the latest of a series of events which began with volcanism, producing felsic and andesitic volcanic rocks which overlie basement in this area. Subsequent periods of tectonism produced large faults along which rhyolitic dykes were emplaced. Continued tectonism resulted in reactivation of old faults along which andesitic and dacitic dykes were injected, crosscutting rhyolite dykes in many cases. As volcanic activity waned, the faults remained active, leaving zones of high permeability which acted as conduits for the still active hydrothermal circulation. Veins appear to have been emplaced at low temperature in a circulating hydrothermal system driven by a heat source at depth associated with dykes present in the area. Circulating hydrothermal fluids may have leached gold from the surrounding andesitic volcanics during propylitization. Permeability may have been controlled by faulting, brecciated flow tops and bottoms, and lapilli tuff horizons. Gold was precipitated in highly permeable conduits, such as the Main Fault Zone and breccia bodies.

Gold-rich polymetallic vein deposits, and gold-copper porphyry deposits, occur along a northwesterly trend across the southern Dawson Range. Vein mineralization is hosted by lithologic units ranging from the Proterozoic-Paleozoic. Basement Metamorphic Complex, through the mid-Cretaceous Mt. Nansen volcanics, to the Late Cretaceous Carmacks volcanics. The mineralized areas also contain numerous porphyry dykes that are spatially associated with gold veins, and historically have been thought to be genetically linked to them. Dykes belonging to both the Mt. Nansen and Carmacks Groups are present, although Mt. Nansen dykes are the more common. Dykes proximal to mineralized veins are strongly altered to sericite and clay. Volcanic and subvolcanic rocks of the Mt. Nansen and Carmacks Groups can be distinguished chemically on the basis of their K content; the Mt. Nansen Group is high-K calc-alkaline suite while the Carmacks Group is a shoshonitic suite. Radiometric age determinations constrain the age of the Carmacks Group to approximately 70 Ma, while the age of the Mt. Nansen Group is approximately 105 Ma. K/Ar dates for altered Mt. Nansen dykes, however, range from 94 to 61 Ma, reflecting resetting of Mt. Nansen ages by a Carmacks-age hydrothermal event. This hydrothermal event appears to have been responsible for much of the mineralization in the southern Dawson Range. Alteration in porphyritic dykes proximal to mineralization is characterized by a strong depletion of Na, reflecting the replacement of feldspar by sericite and clay minerals. Altered dykes also display a general depletion in the ore metals Pb, Zn, and Cu, suggesting that these elements were mobilized from the host rocks during alteration and precipitated in nearby gold-rich base metal veins. As, Sb, and Au, however, appear to have been introduced directly form the hydrothermal fluid.

A copy of this thesis is available at the EMR library – QE195 M321. This thesis is available online at https://open.library.ubc.ca/cIRcle/collections/ubctheses/831/items/1.0302650.

Magmatism in the Nahanni region, which defines the eastern extent of the Tintina Gold Province, is generally associated with tungsten mineralization and/or gold-copper-antimony-bismuth-lead-zinc metal occurrences. Intrusions are subalkaline, granitic to granodioritic, and contain several types of textural variations and highly evolved phases. The intrusions range from large composite batholiths to small stocks with associated felsic dykes and veins. Initial U-Pb and Ar-Ar geochronology reveals ages of 97.5-95 Ma with short (0.5-1.5 m.y.) cooling periods, although the intrusion associated with the Cantung tungsten-skarn orebody cooled over a relatively long period (3 m.y.). Magmatism in the area has been interpreted as crustally derived, however, the rare earth element primitive-mantlenormalized profile revealed negative niobium, tantalum and titanium anomalies suggesting an arctype setting. Furthermore, the granites lack volumetrically significant, primary peraluminous mineralogies characteristic of S-type granites.

Several centres of continental volcanism are situated in southern Yukon. Two of these, the Skukum Volcanic Complex and the Bennett Lake Cauldron Complex BLCC are closely associated in space and gross geological characteristics, including their important role as hosts for epithermal precious metal mineralization. The BLCC was studied extensively by Lambert and the Skukum complex is currently under investigation by the author. The Skukum complex was previously thought to represent a similar structural and volcanic setting to the BLCC. Study of the Skukum complex began in the summer of 1982 with the idea that it represented a cauldron subsidence feature and that an improved understanding of its geology would assist in developing potential targets for mineral exploration. The geology in the area is complex due to the discontinuous nature and incomplete exposure of volcanic units and is further complicated by severe faulting. The author found that the Skukum complex differs from the BLCC in three respects:: 1) the presence of a bimodal suite of extrusive rocks (which suggests the tapping of two magma chambers), 2) its structural complexity and the absence of major cauldron subsidence and 3) the variability of depositional environments within the complex. Contrary to past speculation, the two complexes, which have been considered to be closely related in time and space, each represent a distinctive structural and volcanic setting.

During the 2000 field season, a project was initiated to study the geology, geochemistry and alteration characteristics of high-level subvolcanic porphyritic intrusions associated with the Wolverine volcanic-hosted massive sulphide deposit in the Finlayson Lake district, Yukon. Subvolcanic porphyritic intrusions within the Wolverine deposit are located approximately 10-20 m beneath exhalative sulphide bodies or iron-formation in four zones (Wolverine/Lynx, Fisher, Sable and Puck). Most intrusions are K-feldspar porphyritic (Fisher and Wolverine/Lynx Zones); however, a few are quartz and K-feldspar porphyritic (Puck and Sable zones). Feldspar-porphyritic intrusions consist of euhedral to subhedral grains of K-feldspar in a grey fine-grained matrix. Quartz-feldspar porphyritic intrusions contain slightly smaller feldspar crystals and blue to black glassy quartz eyes set in a fine-grained matrix. Most of the intrusions have non-peperitic upper margins with carbonaceous argillite (Wolverine/Lynx, Fisher, Puck). Some of the quartz- feldspar porphyritic intrusions are in contact with fine-grained volcaniclastic rocks along their upper margins (Sable); both types of intrusions have lower contacts with fine-grained volcaniclastic sedimentary rocks. These intrusions are, for the most part, unaltered and have only minor sericite-silica ±chlorite ±pyrite alteration and small mm-to cm-scale veinlets of quartz-sericite ±chlorite ±pyrite ± sphalerite. This suggests a pre-to syn-mineralization timing for the emplacement of the intrusions. The contribution of these intrusions to the heat and metal budget of the Wolverine deposit is the focus of ongoing research.

The upper Sixtymile River area is located approximately 128 km west of Dawson City, Yukon. Lithology in this area consists of Precambrian to Paleozoic metamorphic rocks, Paleozoic ultramafic rocks, Middle Jurassic pegmatitic and aplitic dikes, Upper Cretaceous porphyritic dikes and volcanic rocks with intercalated sedimentary rocks, Quaternary alkaline basaltic dikes and Quaternary alluvial sediments. Precious metal occurrences in these volcanic rocks are divided into two types, based on differences in local distribution, petrology and wall rock alteration: a gold-bearing pyrite-arsenopyrite type and a silver-bearing galena-sphalerite type. Both types are characterized by four stages of mineralization.

The upper Sixtymile River area is located approximately 128 km west of Dawson City, Yukon. Lithology in this area consists of Precambrian to Paleozoic metamorphic rocks, Paleozoic ultramafic rocks, Middle Jurassic pegmatite and aplite dykes, Late Cretaceous porphyritic dykes and volcanic rocks with intercalated sedimentary rocks, Quaternary alkaline basaltic dykes and Quaternary alluvial sediments. Gold bearing, mesothermal quartz-(carbonate)-sulphide veins which trend NNE-SSW are hosted by metamorphic rocks north and south of Sixtymile River. The mesothermal quartz-(carbonate)-sulphide veins are surrounded by successive envelopes of sericitic, K-feldspar and propylitic alteration. Two stages of vein mineralization are recognized in the northern part of the area, and three stages are recognized in the south part. In the northern veins, pyrite, arsenopyrite, pyrrhotite and quartz are intergrown and formed first. These minerals are fractured and healed by second stage minerals, which include galena, sphalerite, chalcopyrite, pyrite, carbonate and minor quartz. Stage I mineralization in the southern veins is represented by quartz, and pyrite containing inclusions of other sulphides. Stage II is the main stage of precious metal enrichment, represented by arsenopyrite and galena which contain tetrahedrite, miagyrite and polybasite exsolutions. Stage I and II minerals are tectonically fractured, and healed by pyrite, sphalerite, chalcopyrite, freibergite and quartz of stage III. In both vein systems, gold enrichment is associated with arsenopyrite and silver enrichment is associated with galena. The evolution of hydrothermal fluids in the northern area is characterized by decreasing temperature (330°C to 280°C), salinity (12.8% wt.-% to 6 wt.-% NaCI equiv.), oxygen activity (log a(O2) = -30 to log a(O2) = -35), and sulphur activity (log a(S2) = -10 to log a(S2) = -12), as well as a slight increase in pH range (from >3.1 - <5.2 to >3.3 - <5.4). In the southern vein system the fluid evolution characterized by a decrease in temperature (330°C to 150°C), salinity (18.3 wt.-% to 10 wt.-% NaCI equiv.), oxygen activity (log a(O2) = -29 to log a (02) = - 52), and sulphur activity (log a(S2) = -9 to log a(S2) = -18, as well as a slight increase in pH range (>3.2 - <5.3 to >4.1 - <5.9). The following conclusions can be drawn about the fluid composition and mineral enrichment process in the fossil geothermal system of the Sixtymile River area. Deep seated fluids which circulated in the metamorphic rocks were characterized by high temperatures (above 300°C), high salinities (about 18 wt.-% NaCI equiv.) and pH values between 3.1 and 5.2. These fluids are similar to alkaline chloride fluids of active geothermal systems. Arsenic was transported as H3AsO3°-complex, gold as Au(HS)2- and lead, zinc, iron, copper as MeCl2° complexes. The first stage mineralization resulted from reaction of this deep-seated fluid with the wall rock. Second and third stage mineralization is believed to result from the mixing of two fluids with different physico-chemical characteristics.

Description and analysis of the geology of quartz veins containing gold ores in the Yukon Territory.

We present new field and U-Pb analytical data from the Sonora Gulch Project that demonstrate a protracted history of polymetallic mineralization (Au-Ag-Cu-Zn ± Mo) associated with several pulses of Cretaceous magmatism. Recent exploration on the Sonora Gulch Project has highlighted the presence of two important mineralized zones: the Nightmusic zone, a mesothermal Au-enriched base metal skarn, and the Amadeus zone, an epithermal Au-Ag system. Four U-Pb age dates determined from each of two feldspar porphyry dykes (ca. 74 Ma), a weakly mineralized quartz porphyry stock (ca. 75 Ma) within the Nightmusic zone and the Au-Ag mineralized Amadeus stock (ca. 75 Ma), demonstrate the widespread occurrence of Late Cretaceous magmatism. The age determinations indicate that mineralization occurring within the Sonora Gulch project area are temporally equivalent to the Casino Cu-Au-Mo deposit, located roughly 40 km to the west-northwest. These new data extend the currently known eastern limit of Late Cretaceous magmatism and associated mineralization.