Human-use pharmaceutical, pesticide, and wastewater indicator compounds were analyzed at the U.S. Geological Survey, National Water Quality Laboratory, Denver, Colorado, in wadeable streams in 4 Regional Stream Quality Assessments: Northeast (NESQA), Southeast (SESQA), Pacific Northwest (PNSQA) and California (CSQA). Multiple (with few exceptions) samplings occurred at each site, during base flow, between 2014 and 2017. Sites were located in the headwaters of perennial, wadeable streams in urban and agricultural watersheds. Site selection and methodology for each assessment can be found in Van Meter and others (2015), Sheibley and others (2015), Van Meter and others (2017), Coles and others (2016), Van Meter and others (2016), Journey and others (2015), and Van Meter and others (2014). Additional results for this study can be found in Bradley and others, 2020 and Mahler and others, 2020. See cross-reference section for full citation information.

This dataset presents the results of 475 unique organic compounds collected from 54 wadeable streams within the Southeastern, USA, collected within 10 weeks during 2014. Maximum and median exposure conditions were evaluated in relation to watershed characteristics and for potential biological effects. This dataset contains the summary statistics (maximum and median concentrations)of detected compounds, as well as a summary of quality-assurance (blanks and replicates) samples. Also included are the statistical summaries as related to analyte specific contaminant detection/concentration data and site-specific land-use matrices, spearman-rank correlations, and ToxCast evaluations.

This dataset presents the results of 475 unique organic compounds collected from 54 wadeable streams within the Southeastern, USA, collected within 10 weeks during 2014. Maximum and median exposure conditions were evaluated in relation to watershed characteristics and for potential biological effects. This dataset contains the summary statistics (maximum and median concentrations)of detected compounds, as well as a summary of quality-assurance (blanks and replicates) samples. Also included are the statistical summaries as related to analyte specific contaminant detection/concentration data and site-specific land-use matrices, spearman-rank correlations, and ToxCast evaluations.

Human-use pharmaceutical compounds were analyzed at the U.S. Geological Survey, National Water Quality Laboratory, Denver, Colorado, in wadeable streams in 4 Regional Stream Quality Assessments: Northeast (NESQA), Southeast (SESQA), Pacific Northwest (PNSQA) and California (CSQA). Multiple (with few exceptions) samplings occurred at each site, during base flow, between 2014 and 2017. Sites were located in the headwaters of perennial, wadeable streams in urban and agricultural watersheds. Site selection and methodology for each assessment can be found in Van Meter and others (2015), Sheibley and others (2015), Van Meter and others (2017), Coles and others (2016), Van Meter and others (2016), Journey and others (2015), and Van Meter and others (2014).

Human-use pharmaceutical compounds were analyzed at the U.S. Geological Survey, National Water Quality Laboratory, Denver, Colorado, in wadeable streams in 4 Regional Stream Quality Assessments: Northeast (NESQA), Southeast (SESQA), Pacific Northwest (PNSQA) and California (CSQA). Multiple (with few exceptions) samplings occurred at each site, during base flow, between 2014 and 2017. Sites were located in the headwaters of perennial, wadeable streams in urban and agricultural watersheds. Site selection and methodology for each assessment can be found in Van Meter and others (2015), Sheibley and others (2015), Van Meter and others (2017), Coles and others (2016), Van Meter and others (2016), Journey and others (2015), and Van Meter and others (2014).

Surface-water organic contaminant concentration data for targeted chemical analysis of over 800 organic analytes in surface water from 38 stream site representing national gradients in urban and agricultural land use in the USA during 2012-14. ScienceBase Data Release for journal article entitled, "Expanded Target-Chemical Analysis Reveals Extensive Mixed-Organic-Contaminant Exposure in USA Streams"

Surface-water organic contaminant concentration data for targeted chemical analysis of over 800 organic analytes in surface water from 38 stream site representing national gradients in urban and agricultural land use in the USA during 2012-14. ScienceBase Data Release for journal article entitled, "Expanded Target-Chemical Analysis Reveals Extensive Mixed-Organic-Contaminant Exposure in USA Streams"

Filtered water samples were collected by the USGS National Water Quality Program (NWQP) Southeastern Stream Quality Assessment (SESQA) from 59 perennial, wadeable (less than 10 m width and 1 m depth at base-flow) headwater stream sites in watersheds with varying degrees of urban land use in four states. Dataset includes sample site locations and information, analytical method information, water sample pharmaceutical concentrations and summary statistics, and corresponding watershed land-use-land-cover data and data dictionary.

Filtered water samples were collected by the USGS National Water Quality Program (NWQP) Southeastern Stream Quality Assessment (SESQA) from 59 perennial, wadeable (less than 10 m width and 1 m depth at base-flow) headwater stream sites in watersheds with varying degrees of urban land use in four states. Dataset includes sample site locations and information, analytical method information, water sample pharmaceutical concentrations and summary statistics, and corresponding watershed land-use-land-cover data and data dictionary.

The National Water-Quality Assessment (NAWQA) Program and National Stream Quality Accounting Network (NASQAN) are U.S. Geological Survey (USGS) monitoring programs that measure pesticide concentrations in the Nation’s streams and rivers, herein collectively referred to as streams. The NAWQA Program began monitoring pesticides in 1992 and the NASQAN Program began monitoring pesticides in 1995. The programs were recently merged to form the USGS National Water Quality Network for Rivers and Streams. Water samples are analyzed for pesticides by the USGS National Water Quality Laboratory (NWQL) using methods developed by the NWQL’s Methods Research and Development team. The NWQL extensively used two analytical methods, gas chromatography/mass spectrometry and liquid chromatography/mass spectrometry, to measure pesticides in filtered water samples during 1992–2012 (old method). In October 2012, the monitoring programs began using direct aqueous-injection liquid chromatography tandem mass spectrometry as a new analytical method for pesticides (new method). The change in analytical methods, however, has the potential to inadvertently introduce bias in analysis of datasets that span the change. The data sets provided in this report were used to document performance of the new method in a variety of stream-water matrices and help quantify potential changes in measurement bias or variability that could be attributed to changes in analytical methods (Martin and others, 2016). Users should consult the report by Martin and others (2016) to understand how these data were collected and used. Measured concentrations and calculated recoveries of 281 pesticides and degradates in paired environmental background water samples and matrix spiked water samples collected at 48 stream-water sites from June 11, 2012 to September 6, 2012 are provided in seven tab-delimited ASCII files with relational database (RDB) format header. A tab-delimited ASCII file (DataDictionaryList.txt) listing DataSet attributes and RDB column formats is also included in this data release. Martin, J.D., Norman, J.E., Sandstrom, M.W., and Rose, C.E., 2016, A field study of selected U.S. Geological Survey analytical methods for measuring pesticides in filtered stream water, June-September 2012: U.S. Geological Survey Scientific Investigations Report, 2017-5049