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Sampling site information, well construction details, and data dictionaries for data sets associated with the National Crude Oil Spill Fate and Natural Attenuation Site near Bemidji, Minnesota (ver. 4.0, September 2025)
This U.S. Geological Survey data release provides detailed sampling site information, hole and well construction details, and data dictionaries necessary to interpret historical and future physical, chemical, and biological data sets derived from samples collected and measurements made in association with the National Crude Oil Spill Fate and Natural Attenuation Research Site. In 1979, a high-pressure pipeline carrying crude oil burst near the city of Bemidji, Minnesota and spilled approximately 1.7 million liters (10,700 barrels) of crude oil into glacial outwash deposits (Essaid and others, 2011). Since 1983, scientists with the U.S. Geological Survey, in collaboration with scientists from academic institutions, industry, and the regulatory community have conducted extensive investigations of multiphase flow and transport, volatilization, dissolution, geochemical interactions, microbial populations, and biodegradation with the goal of providing an improved understanding of the natural processes limiting the extent of hydrocarbon contamination. Long-term field studies at Bemidji have illustrated that the fate of hydrocarbons evolves with time, and a snap-shot study of a hydrocarbon plume may not provide information that is of relevance to the long-term behavior of the plume during natural attenuation. The research at the site has been supported primarily by the U.S. Geological Survey's Toxic Substances Hydrology Program.
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Data Sets from the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota, USA (ver. 4.0, September 2025)
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This U.S. Geological Survey (USGS) Data Release provides data from samples and measurements completed at the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota (Site) since 1983. This is version 3.0 of this data release, and it now contains 11 data sets. The content of these data sets include inorganic and organic chemistry data from water, oil, and sediment samples, hydraulic conductivity data from well slug tests, sediment grain-size distribution data from core samples, and water- and oil-level data. Most of these data sets have been described in previously published peer-reviewed reports. This data release provides data sets that were not included with the original publications in a tabular, database-ready format. Each result value in the data sets is coded to describe the kind of sample collected, the material that was analyzed, the method of analysis, and the publication where the value was originally published. Some sample codes are taken from the U.S. Geological Survey's National Water Information System (NWIS, https://waterdata.usgs.gov/nwis) and the remaining codes were developed specifically for Site data. Data dictionaries containing code definitions are available at a companion data release titled "Sampling site information, well construction details, and data dictionaries for data sets associated with the National Crude Oil Spill Fate and Natural Attenuation Site near Bemidji, Minnesota", available at https://doi.org/10.5066/F7736PDR. The National Crude Oil Spill Fate and Natural Attenuation Research Site is located where a high-pressure pipeline carrying crude oil burst in 1979 and spilled approximately 1.7 million liters (10,700 barrels) of crude oil into glacial outwash deposits. Since 1983, scientists with the U.S. Geological Survey, in collaboration with scientists from academic institutions, industry, and the regulatory community have conducted extensive investigations of multiphase flow and transport, volatilization, dissolution, geochemical interactions, microbial populations, and biodegradation with the goal of providing an improved understanding of the natural processes limiting the extent of hydrocarbon contamination. Long-term field studies at Bemidji have illustrated that the fate of hydrocarbons evolves with time, and a snap-shot study of a hydrocarbon plume may not provide information that is of relevance to the long-term behavior of the plume during natural attenuation. The research at the site has been supported primarily by the U.S. Geological Survey's Toxic Substances Hydrology Program.
Historical data sets including inorganic and organic chemistry of water, oil, and sediments, aquifer hydraulic conductivity, and sediment grain size distribution at the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota, USA, 1984-2010 (ver 2.0, September 2019)
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This U.S. Geological Survey (USGS) Data Release provides analytical data from samples and measurements completed at the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota (Site) between 1984 and 2010. Included are inorganic and organic chemistry data from water, oil, and sediment samples, hydraulic conductivity data from well slug tests, and sediment grain-size distribution data from core samples. Most of these data sets have been described in previously published peer-reviewed reports, however the tabular data sets were not available with these publications. This data release provides the data in a tabular, database-ready format. Each result value in the data sets is coded to describe the kind of sample collected, the material that was analyzed, the method of analysis, and the publication where the value was originally published. Some sample codes are taken from the U.S. Geological Survey's National Water Information System (NWIS, https://waterdata.usgs.gov/nwis) and the remaining codes were developed specifically for Site data. Data dictionaries containing code definitions are available at a companion data release titled "Sampling site information, well construction details, and data dictionaries for data sets associated with the National Crude Oil Spill Fate and Natural Attenuation Site near Bemidji, Minnesota", available at https://doi.org/10.5066/F7736PDR. In 1979, a high-pressure pipeline carrying crude oil burst near the city of Bemidji, Minnesota and spilled approximately 1.7 million liters (10,700 barrels) of crude oil into glacial outwash deposits. Since 1983, scientists with the U.S. Geological Survey, in collaboration with scientists from academic institutions, industry, and the regulatory community have conducted extensive investigations of multiphase flow and transport, volatilization, dissolution, geochemical interactions, microbial populations, and biodegradation with the goal of providing an improved understanding of the natural processes limiting the extent of hydrocarbon contamination. Long-term field studies at Bemidji have illustrated that the fate of hydrocarbons evolves with time, and a snap-shot study of a hydrocarbon plume may not provide information that is of relevance to the long-term behavior of the plume during natural attenuation. The research at the site has been supported primarily by the U.S. Geological Survey's Toxic Substances Hydrology Program.
Inorganic and organic chemical composition of groundwater collected from monitoring wells located at the National Crude Oil Spill Fate and Natural Attenuation Research Site, Bemidji, Minnesota, USA 2009-2023
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This dataset contains information from groundwater monitoring wells at the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota, USA. The information includes field and laboratory methods, site locations, and inorganic and organic chemistry data. Samples were collected between 2009 and 2023, and analyzed for inorganic anions: F (fluoride), Cl (chloride), Br (bromide), NO3 (nitrate), PO4 (phosphate), SO4 (sulfate), and cations: Ca (calcium), Na, (sodium), Mg (magnesium), K (potassium), Si (silicon), Sr (strontium), Al (aluminum), Fe (iron), Mn (manganese), Ba (barium), B (boron), Li (lithium), Ag (silver), As (arsenic), Be (beryllium), Bi (bismuth), Cd (cadmium), Ce (cerium), Co (cobalt), Cs (cesium), Cr (chromium), Cu (copper), La (lanthanum), Mo (molybdenum), Ni (nickel), Pb (lead), Rb (rubidium), Sb (antimony), Se (selenium), Sn (tin), Th (thorium), Tl (thallium), U (uranium), V (vanadium), W (tungsten), and Zn (zinc). Additionally, samples were analyzed for benzene, toluene, ethylbenzene, o, m, p-xylene, total VHC (30 volatile hydrocarbons), NVDOC (non-volatile dissolved organic carbon), methane, ammonia as nitrogen, alkalinity as HCO3 (bicarbonate), and LMWOA (low molecular weight organic acids; lactate, acetate, propionate, formate, butyrate, pyruvate, and benzoate). The following analyses were performed during a select number of years: delta 13C of DIC (dissolved inorganic carbon) delta 13C of DOC, (dissolved organic carbon) and delta 2H in H2O, delta 18O in H2O. Field measurements for specific conductance, pH, and dissolved oxygen were measured daily. Water levels were measured during the sampling events. The supporting metadata files contain site information, field and laboratory methods, water chemistry, and quality-control results. There are three tables.
Inorganic and organic chemical composition of groundwater collected from monitoring wells located at the National Crude Oil Spill Fate and Natural Attenuation Research Site, Bemidji, Minnesota, USA 2009-2023
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This dataset contains information from groundwater monitoring wells at the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, Minnesota, USA. The information includes field and laboratory methods, site locations, and inorganic and organic chemistry data. Samples were collected between 2009 and 2023, and analyzed for inorganic anions: F (fluoride), Cl (chloride), Br (bromide), NO3 (nitrate), PO4 (phosphate), SO4 (sulfate), and cations: Ca (calcium), Na, (sodium), Mg (magnesium), K (potassium), Si (silicon), Sr (strontium), Al (aluminum), Fe (iron), Mn (manganese), Ba (barium), B (boron), Li (lithium), Ag (silver), As (arsenic), Be (beryllium), Bi (bismuth), Cd (cadmium), Ce (cerium), Co (cobalt), Cs (cesium), Cr (chromium), Cu (copper), La (lanthanum), Mo (molybdenum), Ni (nickel), Pb (lead), Rb (rubidium), Sb (antimony), Se (selenium), Sn (tin), Th (thorium), Tl (thallium), U (uranium), V (vanadium), W (tungsten), and Zn (zinc). Additionally, samples were analyzed for benzene, toluene, ethylbenzene, o, m, p-xylene, total VHC (30 volatile hydrocarbons), NVDOC (non-volatile dissolved organic carbon), methane, ammonia as nitrogen, alkalinity as HCO3 (bicarbonate), and LMWOA (low molecular weight organic acids; lactate, acetate, propionate, formate, butyrate, pyruvate, and benzoate). The following analyses were performed during a select number of years: delta 13C of DIC (dissolved inorganic carbon) delta 13C of DOC, (dissolved organic carbon) and delta 2H in H2O, delta 18O in H2O. Field measurements for specific conductance, pH, and dissolved oxygen were measured daily. Water levels were measured during the sampling events. The supporting metadata files contain site information, field and laboratory methods, water chemistry, and quality-control results. There are three tables.
Ecomapper water-quality data at unnamed north lake near Bemidji, Minnesota, 2019
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These data were collected in cooperation with the U.S. Geological Survey Hydrogeophysics Branch for the National Crude Oil Spill Fate and Natural Attenuation Research Site. Water-quality data were collected using an Ecomapper Autonomous Underwater Vehicle (AUV) and measured parameters include temperature, specific conductance, salinity, water density, pH, dissolved oxygen, total chlorophyll, and blue-green algae. These data are provided in two formats: a CSV file named AUV_WQ_North.csv, and in the Environmental Systems Research Institute (ESRI) shapefile format consisting of a group of files that have been compressed into a zip archive that is named AUV_WQ_North_shapefile.zip.
Ecomapper water-quality data at unnamed north lake near Bemidji, Minnesota, 2019
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These data were collected in cooperation with the U.S. Geological Survey Hydrogeophysics Branch for the National Crude Oil Spill Fate and Natural Attenuation Research Site. Water-quality data were collected using an Ecomapper Autonomous Underwater Vehicle (AUV) and measured parameters include temperature, specific conductance, salinity, water density, pH, dissolved oxygen, total chlorophyll, and blue-green algae. These data are provided in two formats: a CSV file named AUV_WQ_North.csv, and in the Environmental Systems Research Institute (ESRI) shapefile format consisting of a group of files that have been compressed into a zip archive that is named AUV_WQ_North_shapefile.zip.
Ecomapper water-quality data at unnamed south lake near Bemidji, Minnesota, 2019
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These data were collected in coordination with the U.S. Geological Survey Hydrogeophysics Branch for the National Crude Oil Spill Fate and Natural Attenuation Research Site. Water quality data were collected using an Ecomapper Autonomous Underwater Vehicle (AUV) and measured parameters include temperature, specific conductance, salinity, water density, pH, dissolved oxygen, total chlorophyll, and blue-green algae. These data are provided in two formats: a CSV file named AUV_WQ_South.csv, and in the Environmental Systems Research Institute (ESRI) shapefile format consisting of a group of files that have been compressed into a zip archive that is named AUV_WQ_South_shapefile.zip.
Toxicity Data for Groundwater Contaminated by Petroleum Hydrocarbons near Bemidji, MN (2016)
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Management of petroleum-impacted waters by monitored natural attenuation (MNA) requires an understanding of the toxicology of both the original compounds released as well as the transformation products formed during natural breakdown. Here, we report data from a groundwater plume consisting of a mixture of crude oil compounds and transformation products resulting from a crude-oil release in August, 1979 near Bemidji, MN, USA. Water samples were characterized for activation of 52 human nuclear receptor (NR) activities and 50 transcriptional pathways associated with toxic responses. Five replicate analyses were performed for each solution at strengths of 1, 3, and 10 times the sample concentration. Radar plots of the results for each sample and strength are provided.
Analyses of Select Organic and Inorganic Data Collected from Lysimeters Installed at the Bemidji Crude Oil Spill Site, Minnesota, 2018, 2019, 2021
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The U.S. Geological Survey (USGS) collected porewater samples from nine suction lysimeters in 2018, 2019, and 2021 for analysis of organic and inorganic constituents from the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, MN. In August of 1979, approximately 1,700,000 L (liters), or 10,700 barrels, of crude oil spilled onto a glacial outwash aquifer. Sampled lysimeters included L310-1.5, L310-4.5, L1802-1.8, L9014-1.5, L9014-3.0, L9014-4.5, L9017-1.3, L9017-2.5, and L9017-3.7. This data release presents data on analytes that are important indicators of biodegradation processes. Some of these analytes, if present in elevated concentrations, can be a concern regarding potential effects on human health and the environment. There is one tabulated data set containing concentrations of non-volatile dissolved organic carbon (NVDOC), ammonium (NH3-N), orthophosphate, alkalinity as bicarbonate (HCO3-), major inorganic anions, cations, and trace elements. The supporting metadata file contains site information, field and laboratory methods, water chemistry, and quality-control results. Samples were analyzed in the Reston Biogeochemical Processes in Groundwater Laboratory (RBPGL) in Reston, VA, and by a contract lab, Meadowlands Environmental Research Institute (MERI) in Lyndhurst, NJ.
Analyses of Select Organic and Inorganic Data Collected from Lysimeters Installed at the Bemidji Crude Oil Spill Site, Minnesota, 2018, 2019, 2021
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The U.S. Geological Survey (USGS) collected porewater samples from nine suction lysimeters in 2018, 2019, and 2021 for analysis of organic and inorganic constituents from the National Crude Oil Spill Fate and Natural Attenuation Research Site near Bemidji, MN. In August of 1979, approximately 1,700,000 L (liters), or 10,700 barrels, of crude oil spilled onto a glacial outwash aquifer. Sampled lysimeters included L310-1.5, L310-4.5, L1802-1.8, L9014-1.5, L9014-3.0, L9014-4.5, L9017-1.3, L9017-2.5, and L9017-3.7. This data release presents data on analytes that are important indicators of biodegradation processes. Some of these analytes, if present in elevated concentrations, can be a concern regarding potential effects on human health and the environment. There is one tabulated data set containing concentrations of non-volatile dissolved organic carbon (NVDOC), ammonium (NH3-N), orthophosphate, alkalinity as bicarbonate (HCO3-), major inorganic anions, cations, and trace elements. The supporting metadata file contains site information, field and laboratory methods, water chemistry, and quality-control results. Samples were analyzed in the Reston Biogeochemical Processes in Groundwater Laboratory (RBPGL) in Reston, VA, and by a contract lab, Meadowlands Environmental Research Institute (MERI) in Lyndhurst, NJ.