Data for "Frequency-comb spectroscopy on pure quantum states of a single molecular ion"
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These data files contain the data for the measured transition frequencies shown in Table I and the traces in Figure 3 of the publication "Frequency-comb spectroscopy on pure quantum states of a single molecular ion," accessible at https://arxiv.org/abs/1911.12808. In this publication we use generally applicable quantum-logic techniques to prepare a trapped molecular ion in a single quantum state, drive terahertz rotational transitions with an optical frequency comb, and read out the molecular state non-destructively, leaving the molecule ready for further manipulation. One file contains data For Table 1. In the measurement of rotational transition frequencies, the intensities of the comb beams are varied to characterize the effect of AC Stark shift, while the intensity ratio between the sigma and pi polarized beams are kept at close to 2. The average intensity of the sigma-polarized comb beam is quantified by measuring the resultant Stark shift, fSS_sigma, on the 729 nm transition of the Ca+ ion, with the Ca+ ion where the CaH+ ion would be during rotational spectroscopy experiments. The other file contains data for Figure 3, (a) Spectra for the J = 4 to 2 transition: 40CaH+ is prepared in J = 2, followed by a pulse train from the comb Raman beams probing the J = 2 to J = 4 transition. After the probe pulse train, projective measurements of both initial and final states are performed and the state occupation probability is determined. The probe time is ~1.6 ms. The frequency shows the offset of the Raman difference frequency from the resonant value. (b) Rabi flopping on the J = 4 to J = 2 transition: Starting in J = 4, with the comb Raman pulse detuning set to resonance, the state of the 40CaH+ ion is driven coherently to J = 2 by a pulse train of variable duration from the comb Raman beams. The center wavelength of the frequency comb was ~800 nm for these spectra and Rabi flopping traces. The error bars stand for ±1 standard deviation.
Data for "Quantum state tracking and control of a single molecular ion in a thermal environment''
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Supplementary data for the article "Quantum state tracking and control of a single molecular ion in a thermal environment" by Yu Liu, Julian Schmidt, Zhimin Liu, David R. Leibrandt, Dietrich Leibfried, Chin-wen Chou, submitted to Science in 2024. The manuscript describes a quantum state-specific investigation of the molecular state evolution of a single CaH+ ion in a thermal environment. The molecular state can be tracked in real time with single quantum-state resolution and the thermal radiation-induced transitions can be reversed with coherent molecular state manipulation according to the outcomes of state measurements. Results on the transition rates are used to infer the properties of the thermal environment. The data may be used to reproduce the plots shown in the figures.
Data associated with "Primary quantum thermometry of mm-wave blackbody radiation via induced state transfer in Rydberg states of cold atoms"
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Rydberg states of alkali atoms are highly sensitive to electromagnetic radiation in the GHz-to-THz regime because their transitions have large electric dipole moments. Consequently, environmental blackbody radiation (BBR) can couple Rydberg states together at ?s timescales. Here, we track the BBR-induced transfer of a prepared Rydberg state to its neighbors and use the evolution of these state populations to characterize the BBR field at the relevant wavelengths, primarily at 130 GHz. We use selective field ionization readout of Rydberg states with principal quantum number n?30 in 85Rb and substantiate our ionization signal with a theoretical model. With this detection method, we measure the associated blackbody-radiation-induced time dynamics of these states, reproduce the results with a simple semi-classical population transfer model, and demonstrate that this measurement is temperature sensitive with a statistical sensitivity to the fractional temperature uncertainty of 0.09 Hz?1/2, corresponding to 26 K?Hz?1/2 at room temperature. This represents a calibration-free SI-traceable temperature measurement, for which we calculate a systematic fractional temperature uncertainty of 0.006, corresponding to 2 K at room temperature when used as a primary temperature standard.Included in this dataset is the data associated with every plot in the paper, separated by figure number.