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Pipe scale analysis
A calcium phosphate solid formed as an unintended consequence of a novel high-pH orthophosphate lead corrosion control strategy in Providence, RI, causing some consumer complaints and clogged plumbing. The calcium phosphate initially precipitated at orthophosphate doses above about 2 mg/L as PO4 during field testing, and the extent of precipitation increased with water age and higher temperature. Lab scale tests confirmed that doses above about 2 mg/L were required to form the precipitate in the absence of pre-existing calcium phosphate solids, and that the solid formed quickly at 60 °C (upper range for hot water heaters) and tended to dissolve at lower pH. Solubility modeling and other techniques suggest the solids are a mixture of compounds. For water systems currently practicing a high pH/low alkalinity corrosion control strategy, orthophosphate dosing can enhance plumbosolvency control without risky pH reduction, but calcium hardness puts a constraint on the maximum orthophosphate level that can be applied and tolerated. This dataset is associated with the following publication: Devine, C., K. Mello, M. Desantis, M. Schock, J. Tully, and M. Edwards. Calcium Phosphate Precipitation as an Unintended Consequence of Phosphate Dosing to High-pH Water. ENVIRONMENTAL ENGINEERING SCIENCE. Mary Ann Liebert, Inc., Larchmont, NY, USA, 41(5): 171-215, (2024).
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연관 데이터
TullyJennifer A-sj4n SDMP 20200303
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Calculations and the underlying data used to characterize and describe the calcium-lead phosphate minerals identified in lead service line pipe scales. This dataset is associated with the following publication: DeSantis, M., M. Schock, J. Tully, and C. Bennett-Stamper. Orthophosphate Interactions with Destabilized PbO2 Scales. ENVIRONMENTAL SCIENCE & TECHNOLOGY. American Chemical Society, Washington, DC, USA, 54(22): 14302–14311, (2020).
TullyJennifer A-sj4n SDMP 20200303
공공데이터포털
Calculations and the underlying data used to characterize and describe the calcium-lead phosphate minerals identified in lead service line pipe scales. This dataset is associated with the following publication: DeSantis, M., M. Schock, J. Tully, and C. Bennett-Stamper. Orthophosphate Interactions with Destabilized PbO2 Scales. ENVIRONMENTAL SCIENCE & TECHNOLOGY. American Chemical Society, Washington, DC, USA, 54(22): 14302–14311, (2020).
R5 Scale Project Pipe Scale Mineralogy
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The dataset contains reviewed and collected data for: lead profile sampling at different sites and systems; figures classifying observed scale mineralogy; comparisons of adjusted first-draw concentrations compared to LSL sample concentrations, and some maps of interior plumbing to accompany the lead profile sampling. This dataset is associated with the following publication: Tully, J., M. DeSantis, and M. Schock. Water quality-pipe deposit relationships in Midwestern lead pipes. JOURNAL OF THE AMERICAN WATER WORKS ASSOCIATION. American Water Works Association, Denver, CO, USA, 1(2): 1-18, (2019).
Scale Formation under Blended Phosphate Treatment for a Utility with Lead Pipes
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Tap water lead profiles from the Del Toral et al (2013) study, grouped in disturbed and undisturbed Pb service line sites. This dataset is associated with the following publication: Wasserstrom, L., S. Miller , S. Triantafyllidou, M. DeSantis, and M. Schock. Scale Formation under Blended Phosphate Treatment for a Utility with Lead Pipes. Journal AWWA. American Water Works Association, Denver, CO, USA, 109(11): E464-E478, (2017).
Data in figures
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The data resulted from bench and other studies, and were used to produce manuscript plots. This dataset is associated with the following publication: Lytle, D., M. Schock, J. Leo, and B. Barnes. A Model for Estimating the Impact of Orthophosphate on Copper in Water. JOURNAL OF THE AMERICAN WATER WORKS ASSOCIATION. American Water Works Association, Denver, CO, USA, 110(10): E1-E15, (2018).
Streamflow and total phosphorus and orthophosphate data for samples collected in and near the Assabet River, Massachusetts, October 2008 through April 2014
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Streamflow and phosphorus concentrations were monitored in the Assabet River in central Massachusetts in order to evaluate concentrations and loads in the river before, during, and after changes in the amount of total phosphorus that was discharged to the river from three wastewater-treatment plants. At four locations the U.S. Geological Survey collected weekly flow-proportional, composite samples of water from the Assabet River for analysis of concentrations of total phosphorus and orthophosphate. Streamflow and concentration data were used to estimate total phosphorus and orthophosphate loads in the river and compare them with total phosphorus load outputs from three wastewater-treatment plants. Data were collected from October 2008 through April 2014. The data are analyzed in a report that describes changes in phosphorus concentrations and loads during the study period. This data release consists of tables of (1) instream daily streamflow, concentrations of total phosphorus and orthophosphate from weekly composite samples, and daily load estimates for the four monitoring stations on the Assabet River; (2) daily outflow, daily measured and estimated total phosphorus and concentrations, and daily total phosphorus load estimates from the three wastewater-treatment plants; and (3) concentrations of total phosphorus and orthophosphate, and associated daily mean streamflows, for quality-control samples collected for the project.
Simulated orthophosphate concentrations as a function of season and flow for 53 monitoring stations in the Chesapeake Bay watershed for the years 2006 and 2014
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This data release contains simulated orthophosphate concentrations (milligrams per liter) as a function of year, season, and flow for 53 monitoring stations in the Chesapeake Bay watershed. These data were generated for a study published in Science of the Total Environment (https://doi.org/10.1016/j.scitotenv.2018.10.062). They were extracted from the Weighted Regressions in Time, Discharge and Season (WRTDS; Hirsch et al. 2010) models developed for each monitoring station using two functions in the EGRET R package: the flowDuration function and the plotConcTimeSmooth function. The flowDuration function in the EGRET package (Hirsch and DeCicco, 2015) was used to quantify the 5th and 95th percentile flows to represent low and high flows, respectively, for each season at each watershed. These discharge values are then used as input for the plotConcTimeSmooth function, along with a date to represent the midpoint of each calendar year season (January-March = winter, etc.). The midpoints for the seasons were 15-February, 15-May, 15-August, and 15-November for the winter, spring, summer, and fall seasons, respectively. The plotConcTimeSmooth function provides estimates of concentration for those dates at those flows for all years included in the analysis. Simulated concentrations for the years 2006 and 2014 were extracted from this output, and are the only years included in this data release. Sources: Hirsch, R.M., Moyer, D.L., and Archfield, S.A., 2010, Weighted regressions on time, discharge, and season (WRTDS), with an application to Chesapeake Bay river inputs: Journal of the American Water Resources Resources Association, v. 46, no. 5, p. 857-880 Hirsch, R.M. and De Cicco, Laura, 2015, User guide to Exploration and Graphics for RivEr Trends (EGRET) and dataRetrieval: R packages for hydrologic data (version 2.0, February 2015): U.S. Geological Survey Techniques and Methods book 4, chap. A10, 93 p., http://dx.doi.org/10.3133/tm4A10.(accessed May 24, 2018)