This NCEI accession consists of dissolved inorganic carbon, total alkalinity, pH, water temperature and salinity measured from discrete surface samples, taken at the site of GraysRf_81W_31N mooring in Gray’s Reef National Marine Sanctuary, East Coast of the United States on 2024-05-26. Operation of the Grays Reef time-series mooring has been a multi-organization effort which has successfully collected high-resolution data since 2006. The mooring is located in the South Atlantic Bight offshore Georgia, USA and within the boundaries of Gray’s Reef National Marine Sanctuary. It sits along the divide between the inner and middle shelf with water depths of 20 m. Water chemistry is primarily controlled by the middle shelf oceanic dynamics, but during heavy rain events, it can be affected by freshwater plumes coming from the numerous rivers along the Georgia and South Carolina coast. Temperature also plays a major role in the partial pressure of carbon dioxide (pCO2) variability with seasonal changes being apparent. During summer months, GRNMS acts as a CO2 source to the atmosphere while during winter months it is a CO2 sink. The benthic community at GRNMS has proven to be hardy enduring large seasonal swings of seawater CO2 and pH.

This NCEI accession consists of dissolved inorganic carbon, total alkalinity, pH, water temperature and salinity measured from discrete surface samples, taken at the site of GraysRf_81W_31N mooring in Gray’s Reef National Marine Sanctuary, East Coast of the United States on 2025-02-23. Operation of the Grays Reef time-series mooring has been a multi-organization effort which has successfully collected high-resolution data since 2006. The mooring is located in the South Atlantic Bight offshore Georgia, USA and within the boundaries of Gray’s Reef National Marine Sanctuary. It sits along the divide between the inner and middle shelf with water depths of 20 m. Water chemistry is primarily controlled by the middle shelf oceanic dynamics, but during heavy rain events, it can be affected by freshwater plumes coming from the numerous rivers along the Georgia and South Carolina coast. Temperature also plays a major role in the partial pressure of carbon dioxide (pCO2) variability with seasonal changes being apparent. During summer months, GRNMS acts as a CO2 source to the atmosphere while during winter months it is a CO2 sink. The benthic community at GRNMS has proven to be hardy enduring large seasonal swings of seawater CO2 and pH.

This NCEI accession consists of dissolved inorganic carbon, total alkalinity, pH, water temperature and salinity measured from discrete surface samples, taken at the site of GraysRf_81W_31N mooring in Gray’s Reef National Marine Sanctuary, East Coast of the United States on 2024-12-19. Operation of the Grays Reef time-series mooring has been a multi-organization effort which has successfully collected high-resolution data since 2006. The mooring is located in the South Atlantic Bight offshore Georgia, USA and within the boundaries of Gray’s Reef National Marine Sanctuary. It sits along the divide between the inner and middle shelf with water depths of 20 m. Water chemistry is primarily controlled by the middle shelf oceanic dynamics, but during heavy rain events, it can be affected by freshwater plumes coming from the numerous rivers along the Georgia and South Carolina coast. Temperature also plays a major role in the partial pressure of carbon dioxide (pCO2) variability with seasonal changes being apparent. During summer months, GRNMS acts as a CO2 source to the atmosphere while during winter months it is a CO2 sink. The benthic community at GRNMS has proven to be hardy enduring large seasonal swings of seawater CO2 and pH.

This NCEI accession consists of dissolved inorganic carbon, total alkalinity, pH, water temperature and salinity measured from discrete surface samples, taken at the site of GraysRf_81W_31N mooring in Gray’s Reef National Marine Sanctuary, East Coast of the United States on 2024-03-21. Operation of the Grays Reef time-series mooring has been a multi-organization effort which has successfully collected high-resolution data since 2006. The mooring is located in the South Atlantic Bight offshore Georgia, USA and within the boundaries of Gray’s Reef National Marine Sanctuary. It sits along the divide between the inner and middle shelf with water depths of 20 m. Water chemistry is primarily controlled by the middle shelf oceanic dynamics, but during heavy rain events, it can be affected by freshwater plumes coming from the numerous rivers along the Georgia and South Carolina coast. Temperature also plays a major role in the partial pressure of carbon dioxide (pCO2) variability with seasonal changes being apparent. During summer months, GRNMS acts as a CO2 source to the atmosphere while during winter months it is a CO2 sink. The benthic community at GRNMS has proven to be hardy enduring large seasonal swings of seawater CO2 and pH.

This NCEI accession consists of dissolved inorganic carbon, total alkalinity, pH, water temperature and salinity measured from discrete surface samples, taken at the site of GraysRf_81W_31N mooring in Gray’s Reef National Marine Sanctuary, East Coast of the United States on 2025-06-29. Operation of the Grays Reef time-series mooring has been a multi-organization effort which has successfully collected high-resolution data since 2006. The mooring is located in the South Atlantic Bight offshore Georgia, USA and within the boundaries of Gray’s Reef National Marine Sanctuary. It sits along the divide between the inner and middle shelf with water depths of 20 m. Water chemistry is primarily controlled by the middle shelf oceanic dynamics, but during heavy rain events, it can be affected by freshwater plumes coming from the numerous rivers along the Georgia and South Carolina coast. Temperature also plays a major role in the partial pressure of carbon dioxide (pCO2) variability with seasonal changes being apparent. During summer months, GRNMS acts as a CO2 source to the atmosphere while during winter months it is a CO2 sink. The benthic community at GRNMS has proven to be hardy enduring large seasonal swings of seawater CO2 and pH.

This NCEI accession consists of dissolved inorganic carbon, total alkalinity, pH, water temperature and salinity measured from discrete surface samples, taken at the site of GraysRf_81W_31N mooring in Gray’s Reef National Marine Sanctuary, East Coast of the United States on 2023-12-08. Operation of the Grays Reef time-series mooring has been a multi-organization effort which has successfully collected high-resolution data since 2006. The mooring is located in the South Atlantic Bight offshore Georgia, USA and within the boundaries of Gray’s Reef National Marine Sanctuary. It sits along the divide between the inner and middle shelf with water depths of 20 m. Water chemistry is primarily controlled by the middle shelf oceanic dynamics, but during heavy rain events, it can be affected by freshwater plumes coming from the numerous rivers along the Georgia and South Carolina coast. Temperature also plays a major role in the partial pressure of carbon dioxide (pCO2) variability with seasonal changes being apparent. During summer months, GRNMS acts as a CO2 source to the atmosphere while during winter months it is a CO2 sink. The benthic community at GRNMS has proven to be hardy enduring large seasonal swings of seawater CO2 and pH.

This dataset contains discrete bottle sample data for total Dissolved Inorganic Carbon (DIC) and Total Alkalinity (TAlk) samples, which were collected for validation and internal consistency analyses at the Gray's Reef MAPCO2 system off the coast of Georgia, USA in the South Atlantic Bight (31.400, -80.868). Samples were collected and immediately preserved with 0.2 µL of saturated Mercuric Chloride from 2018 through 2021. Samples were transported to the Cai-Laboratory at the University of Delaware for analysis. DIC is analyzed via a nondispersive infrared laser LICOR analyzer after 1 ml of 10% H3PO4 is injected into the sample and the CO2 gas is “stripped” out. TAlk is measured via Gran titration with HCl to an end-point of pH 3.2. The method precision is >0.1%. This effort was conducted in support of the coastal monitoring and research objectives of the NOAA Ocean Acidification Program (OAP).

Near-shore estuarine and coastal regions are where most recreational fishing and tourism occur, yet they are vastly under-sampled. Their susceptibility to OA is not well understood due to their high biogeochemical variability. These regions are affected by land-side processes such as river discharge and run-offs and ocean-side processes through slope water exchange. A full determination of the carbonate system in these regions in conjunction with open ocean measurements is needed to increase our understanding of the effects of OA on ocean health and fisheries and our ability to predict them. In this project, we propose to augment several observational campaigns by 1) adding a carbonate component to the harmful algal blooms (HABs) monitoring cruises conducted periodically on the Western Florida Shelf in order to study potential links between HABs and OA, 2) renewing our collaboration with select National Parks to complement and enhance our near-shore data collection on the Northern Gulf of America and US East Coast, and 3) complementing our underway surface pCO2 measurements in the Gulf of America and US East Coast with underway total alkalinity measurements to help us improve our fundamental understanding of nearshore OA processes. The addition of these measurements to the current assets already present in the region would enhance our understanding of the linkage between nearshore and open ocean processes and better assess the mechanisms and impacts of OA on the biogeochemistry, biology and their economic consequences.

Near-shore estuarine and coastal regions are where most recreational fishing and tourism occur, yet they are vastly under-sampled. Their susceptibility to OA is not well understood due to their high biogeochemical variability. These regions are affected by land-side processes such as river discharge and run-offs and ocean-side processes through slope water exchange. A full determination of the carbonate system in these regions in conjunction with open ocean measurements is needed to increase our understanding of the effects of OA on ocean health and fisheries and our ability to predict them. In this project, we propose to augment several observational campaigns by 1) adding a carbonate component to the harmful algal blooms (HABs) monitoring cruises conducted periodically on the Western Florida Shelf in order to study potential links between HABs and OA, 2) renewing our collaboration with select National Parks to complement and enhance our near-shore data collection on the Northern Gulf of America and US East Coast, and 3) complementing our underway surface pCO2 measurements in the Gulf of America and US East Coast with underway total alkalinity measurements to help us improve our fundamental understanding of nearshore OA processes. The addition of these measurements to the current assets already present in the region would enhance our understanding of the linkage between nearshore and open ocean processes and better assess the mechanisms and impacts of OA on the biogeochemistry, biology and their economic consequences.